351153-90-7

Basic information

• Product Name: 1-C-[4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl]-4-chlorobenzene
• Synonyms: 1-C-[4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl]-4-chlorobenzene
• CAS NO: 351153-90-7
• Molecular Weight: 324.761
• Mol File: 351153-90-7.mol
• Article Data: 7

Chemical Properties

• CAS DataBase Reference: 1-C-[4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl]-4-chlorobenzene(CAS DataBase Reference)
• NIST Chemistry Reference: 1-C-[4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl]-4-chlorobenzene(351153-90-7)
• EPA Substance Registry System: 1-C-[4,6-di-O-acetyl-2,3-dideoxy-α-D-erythro-hex-2-enopyranosyl]-4-chlorobenzene(351153-90-7)

Safety Data

• Hazardous Substances Data: 351153-90-7(Hazardous Substances Data)

Upstream product

• 14752-66-0 sodium p-chlorobenzenesulphinate 
• 2873-29-2 D-glucal triacetate 
• 1679-18-1 4-Chlorophenylboronic acid 
• 106-39-8 bromochlorobenzene 
• 98-60-2 4-chlorobenzenesulfonyl chloride 

Downstream Products

• 1011254-25-3 (2R,3S,6S)-6-(4-Chloro-phenyl)-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-ol 
• 915772-12-2 Carbonic acid (2R,3S,6S)-6-(4-chloro-phenyl)-2-ethoxycarbonyloxymethyl-3,6-dihydro-2H-pyran-3-yl ester ethyl ester 
• 915772-48-4 1-{4-[(2R,3S,6S)-6-(4-Chloro-phenyl)-2-hydroxymethyl-3,6-dihydro-2H-pyran-3-yloxy]-phenyl}-ethanone 

Relevant articles and documents

Palladium(II) Acetate Catalyzed Stereoselective C-Glycosidation of Peracetylated Glycals with Arylboronic Acids

(matrix presented) Addition of a variety of arylboronic acids to peracetylated glycals takes place in the presence of a catalytic amount of Pd(OAc)2. The reaction involves the syn addition of a σ-aryl-Pd complex to the glycal double bond followed by anti elimination of Pd(OAc)2 to provide a carbon-Ferrier type product. This method provides a practical and convenient stereoselective synthesis of C-arylglycosides.

Desulfitative C-arylation of glycals by using benzenesulfonyl chlorides

The palladium-catalyzed stereoselective synthesis of 2,3-deoxy-C-aryl glycosides was investigated. The strategy is based on the Pd-catalyzed desulfitative Heck coupling of arylsulfonyl chlorides and glycals with good leaving groups. An attempt was made to

Exploring skeletal diversity via ring contraction of glycal-derived scaffolds

(Chemical Equation Presented) Aryl ether C-glycoside scaffolds have been prepared from tri-O-acetyl-D-glucal by C-glycosylation followed by allylic substitution with phenols mediated by Pd(0). The aryl ethers were subjected to either [3,3]-sigmatropic rea