38103-67-2

Basic information

• Product Name: Borane, dicyclohexyloctyl-
• CAS NO: 38103-67-2
• Molecular Formula: C20H39B
• Molecular Weight: 290.341
• Mol File: 38103-67-2.mol
• Article Data: 2

Chemical Properties

• CAS DataBase Reference: Borane, dicyclohexyloctyl-(CAS DataBase Reference)
• NIST Chemistry Reference: Borane, dicyclohexyloctyl-(38103-67-2)
• EPA Substance Registry System: Borane, dicyclohexyloctyl-(38103-67-2)

Safety Data

• Hazardous Substances Data: 38103-67-2(Hazardous Substances Data)

Upstream product

• 111-66-0 oct-1-ene 
• 1022976-48-2 dicyclohexylborane-2-picoline complex 
• 1022976-54-0 dicyclohexylborane-2,3-lutidine 
• 1568-65-6 bis(cyclohexanyl)borane 
• 110-83-8 cyclohexene 

Downstream Products

• 124-19-6 nonan-1-al 
• 2043-61-0 cyclohexanecarbaldehyde 
• 2189-60-8 Octylbenzene 
• 111-86-4 n-Octylamine 
• 108-91-8 cyclohexylamine 
• 544-76-3 Hexadecane 
• 92-51-3 cyclohexylcyclohexane 
• 1795-15-9 1-cyclohexyloctane 

Relevant articles and documents

Capturing HBCy2: Using N,O-Chelated Complexes of Rhodium(I) and Iridium(I) for Chemoselective Hydroboration

1,3-N,O-chelated complexes of RhI and IrI cooperatively and reversibly stabilized the B-H bond of HBCy2 to afford six-membered metallaheterocycles (M=Rh (7) or Ir (8)) having a δ-[M]?H-B agostic interaction. Treatment of these Shimoi-type borane adducts 7 or 8 with both an aldehyde and an alkene resulted in chemoselective aldehyde hydroboration and reformation of the 1,3-N,O-chelated starting material. The observed chemoselectivity is inverted from that of free HBCy2, which is selective for alkene hydroboration.