38614-36-7

Basic information

• Product Name: 2-METHYL-1-PROPENYLMAGNESIUM BROMIDE
• Synonyms: 2-Methyl-1-propenylMagnesiuM broMide solution 0.5 M in THF;2-Methyl-1-propenylMagnesiuM broMide, 0.5 M solution in THF, SpcSeal;2-METHYL-1-PROPENYLMAGNESIUM BROMIDE;2-Methyl-1-propenylmagnesium bromide solution;2-METHYL-1-PROPENYLMAGNESIUM BROMIDE, 0. 5M SOLUTION IN TETRAHYDROFURAN;2-Methyl-1-propenylmagnesium bromide, 0.5 in THF;2-METHYL-1-PROPYLMAGNESIUM BROMIDE0.5M THF;2-Methyl-1-propenylmagnesium bromide solution 0.5 in THF
• CAS NO: 38614-36-7
• Molecular Formula: C₄H₇BrMg
• Molecular Weight: 159.31
• Product Categories: Grignard Reagent;Alkenyl;Grignard Reagents;Organometallic Reagents;Chemical Synthesis;Grignard Reagents;Organometallic Reagents
• Mol File: 38614-36-7.mol
• Article Data: 3

Chemical Properties

• Flash Point: 5 °F
• Appearance: Yellow to dark orange/Solution
• Density: 0.952 g/mL at 25 °C
• CAS DataBase Reference: 2-METHYL-1-PROPENYLMAGNESIUM BROMIDE(CAS DataBase Reference)
• NIST Chemistry Reference: 2-METHYL-1-PROPENYLMAGNESIUM BROMIDE(38614-36-7)
• EPA Substance Registry System: 2-METHYL-1-PROPENYLMAGNESIUM BROMIDE(38614-36-7)

Safety Data

• Hazard Codes: F,C,Xn
• Statements: 11-14/15-19-20/21/22-34-37-40-36/37/38-15
• Safety Statements: 16-26-27-36/37/39-45-43-36/37
• RIDADR: UN 3399 4.3/PG 2
• WGK Germany: 3
• Hazardous Substances Data: 38614-36-7(Hazardous Substances Data)

Usage

Chemical Properties

Yellow to dark orange liquid

Uses

Different sources of media describe the Uses of 38614-36-7 differently. You can refer to the following data:
1. 2-Methyl-1-propenylmagnesium bromide(0.5?M in THF) is a reagent used in many chemical reactions such as in the preparation of biaryls, alkylarenes, alkenylarenes, alkynylalkenones via nucleophilic addition.Used in the study of palladium-catalyzed coupling with aryl tosylates.
2. Used in a synthesis of (2S,3S)-3′-fluoroisoleucine.
3. 2-Methyl-1-propenylmagnesium bromide can be used in a study of a palladium-catalyzed coupling with aryl tosylates.

Upstream product

• 3017-69-4 2-methyl-1-propenylbromide 
• 86537-30-6 1-(p-tolylsulfonyl)bicyclo<1.1.0>butane 

Downstream Products

• 121079-58-1 ((S)-1-Cyclohexylmethyl-2-hydroxy-4-methyl-pent-3-enyl)-carbamic acid tert-butyl ester 
• 131510-70-8 (2-Methyl-2-vinyl-cyclobutyl)-phenyl-methanone 
• 131510-69-5 1-[2-(2-Methyl-propenyl)-2-phenyl-cyclobutyl]-ethanone 
• 86537-35-1 1-Methyl-4-[3-(2-methyl-propenyl)-cyclobutanesulfonyl]-benzene 
• 86537-36-2 1-Methyl-4-[3-(2-methyl-propenyl)-cyclobutanesulfonyl]-benzene 
• 86537-35-1 1-Methyl-4-[3-(2-methyl-propenyl)-cyclobutanesulfonyl]-benzene 
• 104621-21-8 [(1S,2R)-2-Methyl-2-(2-methyl-propenyl)-4-oxo-cyclohexyl]-acetic acid tert-butyl ester 
• 97053-80-0 (2-Methyl-1-propenyl)phosphan 
• 90150-60-0 (+/-)-1-<(4-methylphenyl)sulfonyl>-α-(2-methyl-1-propenyl)-1H-indole-4-methanol 
• 7367-81-9 methyl (E)-oct-2-enoate 
• 144079-84-5 7,8-di(carbomethoxy)-6,8-tetradecadiene 
• 145099-83-8 methyl (Z)-2-(2-methyl-1-propenyl)-2-octenoate 
• 145099-84-9 methyl (E)-2-(2-methyl-1-propenyl)-2-octenoate 
• 109769-55-3 2-((1E,3Z)-3,6-Dimethyl-hepta-1,3,5-trienyl)-1,3,3-trimethyl-cyclohexene 

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