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CAS

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38614-36-7

2-METHYL-1-PROPENYLMAGNESIUM BROMIDE is an organomagnesium reagent with the chemical formula (CH3)2C=CHMgBr, commonly used in various chemical reactions due to its nucleophilic addition properties.

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  • 38614-36-7 Structure

  • Basic information

    1. Product Name: 2-METHYL-1-PROPENYLMAGNESIUM BROMIDE
    2. Synonyms: 2-Methyl-1-propenylMagnesiuM broMide solution 0.5 M in THF;2-Methyl-1-propenylMagnesiuM broMide, 0.5 M solution in THF, SpcSeal;2-METHYL-1-PROPENYLMAGNESIUM BROMIDE;2-Methyl-1-propenylmagnesium bromide solution;2-METHYL-1-PROPENYLMAGNESIUM BROMIDE, 0. 5M SOLUTION IN TETRAHYDROFURAN;2-Methyl-1-propenylmagnesium bromide, 0.5 in THF;2-METHYL-1-PROPYLMAGNESIUM BROMIDE0.5M THF;2-Methyl-1-propenylmagnesium bromide solution 0.5 in THF
    3. CAS NO:38614-36-7
    4. Molecular Formula: C4H7BrMg
    5. Molecular Weight: 159.31
    6. EINECS: N/A
    7. Product Categories: Grignard Reagent;Alkenyl;Grignard Reagents;Organometallic Reagents;Chemical Synthesis;Grignard Reagents;Organometallic Reagents
    8. Mol File: 38614-36-7.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: N/A
    3. Flash Point: 5 °F
    4. Appearance: Yellow to dark orange/Solution
    5. Density: 0.952 g/mL at 25 °C
    6. Refractive Index: N/A
    7. Storage Temp.: N/A
    8. Solubility: N/A
    9. CAS DataBase Reference: 2-METHYL-1-PROPENYLMAGNESIUM BROMIDE(CAS DataBase Reference)
    10. NIST Chemistry Reference: 2-METHYL-1-PROPENYLMAGNESIUM BROMIDE(38614-36-7)
    11. EPA Substance Registry System: 2-METHYL-1-PROPENYLMAGNESIUM BROMIDE(38614-36-7)

  • Safety Data

    1. Hazard Codes: F,C,Xn
    2. Statements: 11-14/15-19-20/21/22-34-37-40-36/37/38-15
    3. Safety Statements: 16-26-27-36/37/39-45-43-36/37
    4. RIDADR: UN 3399 4.3/PG 2
    5. WGK Germany: 3
    6. RTECS:
    7. HazardClass: N/A
    8. PackingGroup: N/A
    9. Hazardous Substances Data: 38614-36-7(Hazardous Substances Data)

38614-36-7 Usage

Uses

Used in Organic Synthesis:
2-METHYL-1-PROPENYLMAGNESIUM BROMIDE is used as a reagent for the preparation of biaryls, alkylarenes, alkenylarenes, and alkynylalkenones, facilitating the formation of these compounds through nucleophilic addition reactions.
Used in Palladium-Catalyzed Coupling Reactions:
2-METHYL-1-PROPENYLMAGNESIUM BROMIDE is used as a reagent in the study of palladium-catalyzed coupling with aryl tosylates, enabling the formation of new chemical bonds and the synthesis of complex organic molecules.
Used in Pharmaceutical Synthesis:
2-METHYL-1-PROPENYLMAGNESIUM BROMIDE is used in the synthesis of (2S,3S)-3′-fluoroisoleucine, a compound with potential pharmaceutical applications.
Used in Research and Development:
2-METHYL-1-PROPENYLMAGNESIUM BROMIDE is used in research and development for studying various chemical reactions and developing new synthetic methods in the field of organic chemistry.

Check Digit Verification of cas no

The CAS Registry Mumber 38614-36-7 includes 8 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 5 digits, 3,8,6,1 and 4 respectively; the second part has 2 digits, 3 and 6 respectively.
Calculate Digit Verification of CAS Registry Number 38614-36:
(7*3)+(6*8)+(5*6)+(4*1)+(3*4)+(2*3)+(1*6)=127
127 % 10 = 7
So 38614-36-7 is a valid CAS Registry Number.

38614-36-7 Well-known Company Product Price

  • Brand
  • (Code)Product description
  • CAS number
  • Packaging
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  • Detail

  • Aldrich

  • (419613)  2-Methyl-1-propenylmagnesiumbromidesolution  0.5 M in THF

  • 38614-36-7

  • 419613-100ML

  • 1,535.04CNY

  • Detail

  • Aldrich

  • (419613)  2-Methyl-1-propenylmagnesiumbromidesolution  0.5 M in THF

  • 38614-36-7

  • 419613-800ML

  • 4,656.60CNY

  • Detail

38614-36-7Relevant articles and documents

Broadly Applicable Stereoselective Syntheses of Serrulatane, Amphilectane Diterpenes, and Their Diastereoisomeric Congeners Using Asymmetric Hydrovinylation for Absolute Stereochemical Control

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supporting information, p. 9868 - 9881 (2018/07/25)

A stereogenic center, placed at an exocyclic location next to a chiral carbon in a ring to which it is attached, is a ubiquitous structural motif seen in many bioactive natural products, including di- and triterpenes and steroids. Installation of these ce

COMPOSITIONS FOR TREATING NEURODEGENERATIVE DISEASES

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Paragraph 0327; 0333, (2018/12/12)

The present disclosure relates to novel compounds, pharmaceutical compositions containing the compounds and methods of using the compounds and pharmaceutical compositions for treating neurodegerative diseases, including Alzheimer's disease and cognitive decline. Methods for inhibiting synapse number decline or membrane trafficking abnormalities associated with exposure of a neuronal cell to Abeta species are also disclosed.

Bridgehead Reactivity, Nucleophilic and Radical Additions, and Lithium Aluminum Hydride Reduction of 1-(Arylsulfonyl)bicyclobutanes: General Access to Substituted, Functionalized Cyclobutanes. Syntheses of (+/-)-Citrilol Acetate, (+/-)-Junionone, and the

Gaoni, Yehiel,Tomazic, Alenka

, p. 2948 - 2957 (2007/10/02)

A general approach to the synthesis of a wide range of substituted cyclobutane derivatives is based on two specific reactions of 1-(arylsulfonyl)bicyclobutanes (1) and on some general reactions of the bicyclobutane ring systems.One specific cyclobutane fo

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