4444-68-2 Usage
Uses
N,N-Diethylbutylamine may be used for the regioselective syntheses of of 6-(1,1-dimethylallyl) ortho-flavones. It was used in the synthesis of N,N-diethylbutylammonium bis(trifluoromethylsulfonyl)imide.
General Description
Light yellow liquid.
Air & Water Reactions
Highly flammable. N,N-DIETHYLBUTYLAMINE may be unstable to prolonged exposure to air. . Insoluble in water.
Reactivity Profile
N,N-DIETHYLBUTYLAMINE neutralizes acids in exothermic reactions to form salts plus water. May be incompatible with isocyanates, halogenated organics, peroxides, phenols (acidic), epoxides, anhydrides, and acid halides. Flammable gaseous hydrogen may be generated in combination with strong reducing agents, such as hydrides.
Health Hazard
ACUTE/CHRONIC HAZARDS: N,N-DIETHYLBUTYLAMINE is flammable and should be kept away from any heat source of heat or ignition.
Fire Hazard
The flash point of N,N-DIETHYLBUTYLAMINE has not been determined, but N,N-DIETHYLBUTYLAMINE is probably flammable.
Check Digit Verification of cas no
The CAS Registry Mumber 4444-68-2 includes 7 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 4 digits, 4,4,4 and 4 respectively; the second part has 2 digits, 6 and 8 respectively.
Calculate Digit Verification of CAS Registry Number 4444-68:
(6*4)+(5*4)+(4*4)+(3*4)+(2*6)+(1*8)=92
92 % 10 = 2
So 4444-68-2 is a valid CAS Registry Number.
InChI:InChI=1/C8H19N/c1-4-7-8-9(5-2)6-3/h4-8H2,1-3H3
4444-68-2Relevant articles and documents
Alkyl coupling in tertiary amines as analog of Guerbet condensation reaction
Zhou, Yage,Wu, Dan,Hernández, Willinton Yesid,Ma, Changru,Su, Huangyang,Ordomsky, Vitaly
, p. 9845 - 9849 (2019/04/01)
We report here that C-C coupling in tertiary amines for the synthesis of long chain and hindered amines might be efficiently performed over Pt and Pd catalysts. The mechanism study confirms similarity with the Guerbet reaction through dehydrogenation of the alkyl group and subsequent attack of the α-carbon atom by an alkyl group of another molecule. Finally, secondary amines and tertiary amines with longer alkyl chains are formed.
A novel method for N-alkylation of aliphatic amines with ethers over ?3-Al2O3
Chen, Hangeng,Zhang, Tao,Qian, Chao,Chen, Xinzhi
, p. 537 - 540 (2015/03/05)
A novel and simple method for the N-alkylation of amines with different ethers as alkylating reagents has been developed, using cheap ?3-Al2O3 as the catalyst at atmospheric pressure in the temperature range of 260-320?°C. For example, the reaction of equ