46346-67-2Relevant articles and documents
REACTION OF TRANSITION METAL CARBONYLS WITH HETEROCYCLIC SYSTEMS. VI. THE INTERACTION OF Fe2(CO)9 WITH N-BENZYLOXYPIPERIDINE AND RELATED COMPOUNDS
Blum, Y.,Becker, Y.,Shvo, Y.
, p. 65 - 76 (1980)
N-Benzyloxypiperidine exhibits an unexpected type of reactivity toward Fe2(CO)9.Benzaldehyde and N-formylpiperidine are formed, most probably in a concerted manner, as revealed by deuterium-labeling experiments.Several mechanistic details of this reaction have been elucidated.The nature of the reaction contrasts with that of N-propyloxy-N-methylaniline, which upon treatment with Fe2(CO)9 undergoes insertion of a CO group into the N-O bond to generate a carbamate.
