530-47-2

Basic information

• Product Name: N,N-Diphenylhydrazinium chloride
• Synonyms: Hydrazine, 1,1-diphenyl-, hydrochloride;N,N-Diphenylhydrazinium chloride for synthesis;1,1-diphenyl-hydrazinmonohydrochloride;N,N-DIPHENYLHYDRAZINE HYDROCHLORIDE;N,N-DIPHENYLHYDRAZINIUM CHLORIDE;TIMTEC-BB SBB003350;ASYM-DIPHENYLHYDRAZINE HYDROCHLORIDE;1,1-DIPHENYLHYDRAZINE HYDROCHLORIDE
• CAS NO: 530-47-2
• Molecular Formula: C₁₂H₁₃N₂*Cl
• Molecular Weight: 220.7
• EINECS: 208-481-0
• Product Categories: Aromatic Hydrazides, Hydrazines, Hydrazones and Oximes;pharmacetical;Phenylhydrazine
• Mol File: 530-47-2.mol

Chemical Properties

• Melting Point: 162-166 °C (dec.)
• Boiling Point: 330 °C at 760 mmHg
• Flash Point: 180.5 °C
• Appearance: white to light yellow crystal powder
• Density: 1.143 g/cm³
• Vapor Pressure: 0.000171mmHg at 25°C
• Storage Temp.: Store below +30°C.
• Water Solubility: soluble
• Merck: 14,3325
• BRN: 3569340
• CAS DataBase Reference: N,N-Diphenylhydrazinium chloride(CAS DataBase Reference)
• NIST Chemistry Reference: N,N-Diphenylhydrazinium chloride(530-47-2)
• EPA Substance Registry System: N,N-Diphenylhydrazinium chloride(530-47-2)

Safety Data

• Hazard Codes: C,Xn
• Statements: 20/21/22-34-36/37/38
• Safety Statements: 26-36/37/39-45
• RIDADR: UN 3261 8/PG 2
• WGK Germany: 3
• RTECS: MV3520000
• F: 8
• TSCA: Yes
• HazardClass: 8
• PackingGroup: III
• Hazardous Substances Data: 530-47-2(Hazardous Substances Data)

Usage

Uses

Used in Organic Synthesis:
N,N-Diphenylhydrazinium chloride is used as a synthetic intermediate for the production of various organic compounds. It is particularly useful in the synthesis of 2-Vinyloxyethyloxy-4-diethylaminophenyl-1-carbaldehyde N,N-diphenylhydrazone, which is a hole-transporting hydrazine. N,N-Diphenylhydrazinium chloride is significant in the development of electronic materials and devices, such as organic light-emitting diodes (OLEDs) and organic photovoltaics (OPVs).
Used in Pharmaceutical Industry:
In the pharmaceutical industry, N,N-Diphenylhydrazinium chloride is utilized as a building block for the synthesis of various pharmaceutical compounds. Its unique chemical properties make it a valuable component in the development of new drugs and therapeutic agents.
Used in Chemical Research:
N,N-Diphenylhydrazinium chloride is also employed in chemical research as a reagent for various analytical and experimental procedures. Its ability to form complexes with other molecules makes it a useful tool for studying chemical reactions and understanding the properties of different compounds.

InChI:InChI=1/C12H12N2.ClH/c13-14(11-7-3-1-4-8-11)12-9-5-2-6-10-12;/h1-10H,13H2;1H

Upstream product

• 530-50-7 1,1-Diphenylhydrazine 
• 1920-15-6 (C₆H₅)2NNH₂*BH₃ 
• 7732-18-5 water 
• 59-88-1 phenylhydrazine hydrochloride 
• 382165-80-2 N-nitrosodiphenylamine 
• 181058-87-7 3-diphenylhydrazono-butyric acid ethyl ester 
• 62758-20-7 6,8-dimethyl-3,5,7-trioxo-2,3,5,6,7,8-hexahydropyrimido[5,4-e][1,2,4]-triazine-4-oxide 

Downstream Products

• 110520-42-8 Chloro-phenyl-acetic acid N',N'-diphenyl-hydrazide 
• 70570-03-5 dinitroformaldehyde diphenylhydrazone 
• 110520-40-6 Chloro-p-tolyl-acetic acid N',N'-diphenyl-hydrazide 
• 181058-87-7 3-diphenylhydrazono-butyric acid ethyl ester 
• 36195-65-0 2,6-Di-tert.butyl-p-benzochinon-4-diphenylhydrazon 
• 6233-05-2 2-acetyl-1,1-diphenylhydrazine 
• 86-74-8 9H-carbazole 
• 122-39-4 diphenylamine 
• 214621-93-9 methyl 2-(diphenylaminoimino)ethanate 
• 652156-73-5 D-glyceraldehyde N,N-diphenylhydrazone 
• 324753-67-5 D-glyceraldehyde N,N-diphenylhydrazone 
• 953054-18-7 C₂₆H₂₃N₃O₂S 
• 856243-12-4 N'-[3-(tert-butyl-dimethyl-silanyloxy)-butylidene]-N,N-diphenyl-hydrazine 
• 82532-76-1 4-Diphenylaminobenzaldehyde diphenylhydrazone 

Relevant articles and documents

PROCESS FOR PRODUCING HYDRAZONE COMPOUND

The present invention provides a process for producing a hydrazone compound represented by the general formula (5): which comprises a step of condensing a hydrazine compound represented by the general formula (3): with a carbonyl compound represented by the general formula (4): without taking the hydrazine compound out of a reactor. According to the invention, the target hydrazone compound can be obtained in high quality and in a high yield without taking the hydrazine compound out of the reactor at all, the hydrazine compound being a reaction intermediate which is structurally unstable and has a fear of influencing safety of workers owing to its toxicity (mutagenicity).

New sulfonyl derivatives of 2,2-diphenyl-1-picrylhydrazyl and their supramolecular complexes with crown ethers or kryptands

The synthesis of mono-and di-sulfonates 1 and 2 derived from DPPH was optimised (their notation is NaOSO2-DPPH and (NaOSO2)2-DPPH, respectively). The pKa values of the corresponding hydrazines 3 and 4 were determined. With crown ether 18-C-6, hydrophobic supramolecular complexes are formed by 3 and 4. The sodium monosulfonate 3 reacts with thionyl chloride yielding the sulfochloride ClSO2-DPPH-H (5). With alcohols or amines, 5 reacts readily leading to alkyl esters and sulfonamide derivatives, respectively: thus, valine afforded a well-characterized compound, and the corresponding free radical may be used as a spin label or as a colored redox indicator for peptide chemistry. Similarly, 4-aminoantipyrine forms a sulfonamide. The new compounds were characterised by elemental analysis, IR, UV-VIS, NMR and ESR spectroscopy, and by their complexation and transport data.