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597-25-1

Dimethyl morpholinophosphoramidate. is a chemical with a specific purpose. Lookchem provides you with multiple data and supplier information of this chemical.

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  • 597-25-1 Structure

  • Basic information

    1. Product Name: Dimethyl morpholinophosphoramidate.
    2. Synonyms: Dimethyl morpholinophosphoramidate.;PHOSPHONICACID,MORPHOLINO-,DIMETHYLESTER;Dimethyl morpholinophosphonate;Morpholinophosphonic acid dimethyl ester;4-dimethoxyphosphorylmorpholine;Dimethyl (morpholin-4-yl)phosphonate
    3. CAS NO:597-25-1
    4. Molecular Formula: C6H14NO4P
    5. Molecular Weight: 195.16
    6. EINECS: N/A
    7. Product Categories: N/A
    8. Mol File: 597-25-1.mol

  • Chemical Properties

    1. Melting Point: N/A
    2. Boiling Point: 42.3°C
    3. Flash Point: 103.1°C
    4. Appearance: /
    5. Density: 1.21g/cm3
    6. Vapor Pressure: 0.0266mmHg at 25°C
    7. Refractive Index: 1.454
    8. Storage Temp.: N/A
    9. Solubility: N/A
    10. CAS DataBase Reference: Dimethyl morpholinophosphoramidate.(CAS DataBase Reference)
    11. NIST Chemistry Reference: Dimethyl morpholinophosphoramidate.(597-25-1)
    12. EPA Substance Registry System: Dimethyl morpholinophosphoramidate.(597-25-1)

  • Safety Data

    1. Hazard Codes: N/A
    2. Statements: N/A
    3. Safety Statements: N/A
    4. WGK Germany:
    5. RTECS:
    6. HazardClass: N/A
    7. PackingGroup: N/A
    8. Hazardous Substances Data: 597-25-1(Hazardous Substances Data)

597-25-1 Usage

General Description

Clear colorless slightly viscous liquid.

Air & Water Reactions

Sensitive to prolonged exposure to air. Water soluble. Slowly hydrolyzes upon exposure to moisture.

Reactivity Profile

Water soluble. Hydrolysis occurs rapidly on exposure to acids.

Health Hazard

ACUTE/CHRONIC HAZARDS: When heated to decomposition Dimethyl morpholinophosphoramidate. emits very toxic fumes of nitrogen oxides and phosphorous oxides.

Fire Hazard

Dimethyl morpholinophosphoramidate. is probably combustible.

Check Digit Verification of cas no

The CAS Registry Mumber 597-25-1 includes 6 digits separated into 3 groups by hyphens. The first part of the number,starting from the left, has 3 digits, 5,9 and 7 respectively; the second part has 2 digits, 2 and 5 respectively.
Calculate Digit Verification of CAS Registry Number 597-25:
(5*5)+(4*9)+(3*7)+(2*2)+(1*5)=91
91 % 10 = 1
So 597-25-1 is a valid CAS Registry Number.
InChI:InChI=1/C6H14NO4P/c1-9-12(8,10-2)7-3-5-11-6-4-7/h3-6H2,1-2H3

597-25-1SDS

SAFETY DATA SHEETS

According to Globally Harmonized System of Classification and Labelling of Chemicals (GHS) - Sixth revised edition

Version: 1.0

Creation Date: Aug 15, 2017

Revision Date: Aug 15, 2017

1.Identification

1.1 GHS Product identifier

Product name 4-dimethoxyphosphorylmorpholine

1.2 Other means of identification

Product number -
Other names Dimethyl morpholinophosphoramidate

1.3 Recommended use of the chemical and restrictions on use

Identified uses For industry use only.
Uses advised against no data available

1.4 Supplier's details

1.5 Emergency phone number

Emergency phone number -
Service hours Monday to Friday, 9am-5pm (Standard time zone: UTC/GMT +8 hours).

More Details:597-25-1 SDS

597-25-1Downstream Products

597-25-1Relevant articles and documents

ON THE REACTION OF BENZOTHIAZOL-2-YL SULPHENAMIDES WITH PHOSPHITES

Brownbridge, P.,Jowett, I. C.

, p. 311 - 318 (2007/10/02)

A study of the synthesis of phosphoramidates from phosphites and benzothiazol-2-yl-sulphenamides, indicates that a quinquecovalent phosphorane is an intermediate.Since the initial step in this reaction does not involve attack of phosphorus on nitrogen, it is unlikely that these sulphenamides will act as electrophilic aminating agents towards non-phosphorus nucleophiles.An efficient new method for preparing benzothiazol-2-yl-sulphenamides is reported.

SOLVOLYSIS OF DIPHENYL AMIDOPHOSPHATES IN AQUEOUS ALCOHOLIC MEDIA

Kasparek, Frantisek,Mollin, Jiri

, p. 386 - 396 (2007/10/02)

Influence of substituent on the reaction rate of the alkali-catalyzed solvolysis of the studied compounds set has been followed.The activation entropy has also been determined.The reaction products have been identified, and their concentration ratio has been determined.The reaction selectivity is mostly influenced by sterical effects in the substrate molecule.The results obtained agree with the SN2 mechanism.

REACTION OF SULFENAMIDES WITH DI-ALKYL AND TRIALKYL PHOSPHITES. AN EFFICIENT SYNTHESIS OF PHOSPHORAMIDATES BY UNUSUAL SUBSTITUTION AT S-N BOND IN (2-BENZOTHIAZOLYL)SULFENAMIDES

Torii, Sigeru,Sayo, Noboru,Tanaka, Hideo

, p. 695 - 698 (2007/10/02)

Regioselective attack of the trivalent phosphorus atom of dialkyl and trialkyl phosphites on either nitrogen or sulfur atom of sulfenamides has been found.The reaction of phenylsulfenamides with dialkyl phosphites yielded phosphorothiolates, whereas the treatment of (2-benzothiazolyl)sulfenamides with dialkyl and trialkyl phosphites gave phosphoramidates in excellent yields.

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