622-34-4Relevant articles and documents
The Photolysis of 2-Phenyltetrazole
Koga, Nobuko,Koga, Gen,Springer, James P.,Arison, Byron H.,Anselme, Jean-Pierre
, p. 610 - 612 (1983)
The photolysis of 2-phenyltetrazole (1) in benzene yields phenylcyanamide (27percent) and the phenylhydrazone of o-aminobenzoyl cyanide (53percent) whose structure was determined by X-ray crystal structure analysis.
New compounds: Potential antituberculous agents I: Alkylaryl 4-arylformamidinothiosemicarbazones
Srivastava,Upadhyaya
, p. 904 - 906 (1977)
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Synthesis of nitriles via the iodine-mediated dehydrosulfurization of thioamides
Murata, Yuki,Iwasa, Hitomi,Matsumura, Mio,Yasuike, Shuji
, p. 679 - 681 (2020/07/30)
A simple general method for the synthesis of nitriles using the inexpensive and easy to handle iodine (I2) is described herein. The reaction of thioamides with I2 in the presence of triethylamine at room temperature under aerobic conditions afforded various nitriles bearing aryl, vinyl, and alkyl groups in good-to-excellent yields. This method was also effective for conversion from thioureas to cyanamides.
SO2F2-Mediated one-pot cascade process for transformation of aldehydes (RCHO) to cyanamides (RNHCN)
Ding, Chengrong,Ge, Shuting,Wei, Junjie,Zhang, Guofu,Zhao, Yiyong
, p. 17288 - 17292 (2020/05/18)
A simple, mild and practical cascade process for the direct conversion of aldehydes to cyanamides was developed featuring a wide substrate scope and great functional group tolerability. This method allows for transformations of readily available, inexpensive, and abundant aldehydes to highly valuable cyanamides in a pot, atom, and step-economical manner with a green nitrogen source. This protocol will serve as a robust tool for the installation of the cyanamide moiety in various complicated molecules.