7331-84-2Relevant articles and documents
A Simple Synthesis pf Primary Amines via their N,N-Bis(trimethylsilyl) Derivatives
Bestmann, Hans Juergen,Woelfel, Gerhard
, p. 1250 - 1254 (2007/10/02)
Primary halogen compounds 1 or the corresponding tosylates react with sodium bis(trimethylsilyl)amide (2) in hexamethyldisilazane to form N,N-bis(trimethylsilyl)amines 3, which are converted into the amine hydrochlorides 5 by treatment with aqueous HCl.
N,N-Bis(trimethylsilyl)methoxymethylamine as a Convenient Synthetic Equivalent for +CH2NH2: Primary Aminomethylation of Organometallic Compounds
Morimoto, Toshiaki,Takahashi, Toshio,Sekiya, Minoru
, p. 794 - 795 (2007/10/02)
The introduction of the primary aminomethyl unit at carbon through N,N-bis(trimethylsilyl)aminomethylation of Grignard and organolithium compounds can be achieved in good yield using N,N-bis(trimethylsilyl)methoxymethylamine (1).