74995-86-1

Basic information

• Product Name: Methyl-4-O-benzoyl-2,3,6-tridesoxy-3-C-methyl-α-D-erythro-hex-2-enopyranosid
• Synonyms: Methyl-4-O-benzoyl-2,3,6-tridesoxy-3-C-methyl-α-D-erythro-hex-2-enopyranosid
• CAS NO: 74995-86-1
• Molecular Weight: 262.306
• Mol File: 74995-86-1.mol

Chemical Properties

• CAS DataBase Reference: Methyl-4-O-benzoyl-2,3,6-tridesoxy-3-C-methyl-α-D-erythro-hex-2-enopyranosid(CAS DataBase Reference)
• NIST Chemistry Reference: Methyl-4-O-benzoyl-2,3,6-tridesoxy-3-C-methyl-α-D-erythro-hex-2-enopyranosid(74995-86-1)
• EPA Substance Registry System: Methyl-4-O-benzoyl-2,3,6-tridesoxy-3-C-methyl-α-D-erythro-hex-2-enopyranosid(74995-86-1)

Safety Data

• Hazardous Substances Data: 74995-86-1(Hazardous Substances Data)

Upstream product

• 74995-85-0 Methyl-4-O-benzoyl-2,6-didesoxy-3-C-methyl-α-D-ribo-hexopyranosid 
• 99922-58-4 4-O-Benzoyl-1-O-(4-O-benzoyl-2,3,6-tridesoxy-3-C-methyl-α-D-erythro-hex-2-enopyranosyl)-2,3,6-tridesoxy-3-C-methyl-α-D-erythro-hex-2-enopyranosid 
• 63598-31-2 methyl 4,6-O-(R)-benzylidene-2-deoxy-α-D-erythrohexopyranosid-3-ulose 
• 6752-52-9 Methyl-4,6-O-benzyliden-2-desoxy-3-C-methyl-α-D-ribo-hexopyranosid 
• 74995-84-9 methyl 4-O-benzoyl-6-bromo-2,6-dideoxy-3-C-methyl-α-D-ribo-hexopyranoside 
• 6752-49-4 (4aR,6S,8aR)-6-Methoxy-2-phenyl-tetrahydro-pyrano[3,2-d][1,3]dioxin-8-one 

Downstream Products

• 79437-67-5 3(R)-Methyl-4-O-benzoyl-2,3,6-tridesoxy-3-C-methyl-α-D-erythro-hexopyranosid 
• 79437-67-5 3(S)-Methyl-4-O-benzoyl-2,3,6-tridesoxy-3-C-methyl-α-D-erythro-hexopyranosid 
• 79607-54-8 4-O-Benzoyl-2,3,6-tridesoxy-3-C-methyl-β-D-erythro-hex-2-enopyranose 
• 79607-51-5 4-O-Benzoyl-2,3,6-tridesoxy-3-C-methyl-α-D-erythro-hex-2-enopyranose 
• 99922-58-4 4-O-Benzoyl-1-O-(4-O-benzoyl-2,3,6-tridesoxy-3-C-methyl-α-D-erythro-hex-2-enopyranosyl)-2,3,6-tridesoxy-3-C-methyl-α-D-erythro-hex-2-enopyranosid 
• 78082-55-0 methyl 4-O-benzoyl-6-deoxy-3-C-methyl-α-D-mannopyranoside 
• 115957-15-8 methyl 4-O-benzoyl-6-deoxy-3C-methyl-β-L-mannopyranoside 
• 115957-14-7 methyl 4-O-benzoyl-6-deoxy-3-C-methyl-α-L-mannopyranoside 
• 74995-88-3 Methyl-2,3,4,6-tetradesoxy-3-C-methyl-4-thiophenyl-α-D-threo-hex-2-enopyranosid 
• 74995-89-4 Methyl-2,3,4,6-tetradesoxy-3-C-methyl-4-(phenylsulfinyl)-α-D-threo-hex-2-enopyranosid 
• 74995-92-9 Methyl-2-O-acetyl-4,6-didesoxy-3-C-methyl-4-(p-tolylsulfonylamino)-α-D-altropyranosid 
• 78013-85-1 Methyl-4,6-didesoxy-3-C-methyl-4-(p-tolylsulfonylamino)-α-D-altropyranosid 
• 78013-86-2 Methyl-4,6-didesoxy-3-C-methyl-N-methyl-4-(p-tolylsulfonylamino)-α-D-altropyranosid 
• 104874-61-5 methyl 6-deoxy-3-C-methyl-α-L-mannopyranoside 

Relevant articles and documents

Synthesen biologisch wichtiger Kohlenhydrate, 24. Derivate des Sibirosamins (4,6-Didesoxy-3-C-methyl-4-methylamino-D-altropyranose) durch 4 -> 2-Chiralitaetstransfer und vic. cis-Oxyaminierung eines 3-C-Methyl-hex-3-enopyranosids

Methyl 4-O-benzoyl-2,6-didesoxy-3-C-methyl-α-D-ribo-hexopyranoside (14) yields the D-erythro configurated 3-C-branched hex-2-enopyranosides 15 and 16, resp., with high selectivity by elimination with thionyl chloride. 16 is transformed with complete inver