74995-84-9

Upstream product

• 100100-70-7 methyl 4,6-O-benzylidene-2-deoxy-3-C-methyl-α-D-arabino-hexopyranoside 
• 63598-31-2 methyl 4,6-O-(R)-benzylidene-2-deoxy-α-D-erythrohexopyranosid-3-ulose 
• 72244-36-1 (2R,4aR,6S,8aS)-6-Methoxy-8-methylene-2-phenyl-hexahydro-pyrano[3,2-d][1,3]dioxine 
• 6752-52-9 Methyl-4,6-O-benzyliden-2-desoxy-3-C-methyl-α-D-ribo-hexopyranosid 
• 78086-67-6 methyl-4,6-O-benzylidene-2-desoxy-3-C-methyl-α-D-ribo-hexopyranoside 
• 66183-24-2 1,5-anhydro-4,6-O-benzylidene-2-deoxy-D-erythro-hex-3-ulo-1-enitol 
• 6752-49-4 (4aR,6S,8aR)-6-Methoxy-2-phenyl-tetrahydro-pyrano[3,2-d][1,3]dioxin-8-one 
• 78013-74-8 1,5-Anhydro-4,6-O-benzyliden-2-desoxy-3-C-methyl-D-ribo-hex-1-enit 
• 78013-75-9 Methyl-4,6-O-benzyliden-2-desoxy-2-iod-3-C-methyl-α-D-altropyranosid 

Downstream Products

• 68536-36-7 Benzoic acid (2R,3R,6S)-4-hydroxy-6-methoxy-2,4-dimethyl-tetrahydro-pyran-3-yl ester 
• 74995-85-0 Methyl-4-O-benzoyl-2,6-didesoxy-3-C-methyl-α-D-ribo-hexopyranosid 
• 78013-86-2 Methyl-4,6-didesoxy-3-C-methyl-N-methyl-4-(p-tolylsulfonylamino)-α-D-altropyranosid 
• 78013-83-9 Methyl-4-O-benzoyl-2,3,6-tridesoxy-3-C-methylen-α-D-erythro-hexopyranosid 
• 78013-85-1 Methyl-4,6-didesoxy-3-C-methyl-4-(p-tolylsulfonylamino)-α-D-altropyranosid 
• 74995-92-9 Methyl-2-O-acetyl-4,6-didesoxy-3-C-methyl-4-(p-tolylsulfonylamino)-α-D-altropyranosid 
• 74995-86-1 Methyl-4-O-benzoyl-2,3,6-tridesoxy-3-C-methyl-α-D-erythro-hex-2-enopyranosid 
• 74995-89-4 Methyl-2,3,4,6-tetradesoxy-3-C-methyl-4-(phenylsulfinyl)-α-D-threo-hex-2-enopyranosid 
• 74995-88-3 Methyl-2,3,4,6-tetradesoxy-3-C-methyl-4-thiophenyl-α-D-threo-hex-2-enopyranosid 
• 110906-68-8 C₂₈H₃₆O₇ 
• 110906-68-8 C₂₈H₃₆O₇ 
• 110906-70-2 Benzoic acid (2R,3R,4R,6S)-3-((2R,3S,4S,5R,6R)-4,5-bis-benzyloxy-6-methyl-3-phenylselanyl-tetrahydro-pyran-2-yloxy)-6-methoxy-2,4-dimethyl-tetrahydro-pyran-4-yl ester 
• 110906-66-6 Benzoic acid (2R,3R,4R,6S)-4-((2R,3S,4S,5R,6R)-4,5-bis-benzyloxy-6-methyl-3-phenylselanyl-tetrahydro-pyran-2-yloxy)-6-methoxy-2,4-dimethyl-tetrahydro-pyran-3-yl ester 
• 110906-72-4 C₃₄H₄₂O₈Se 

Relevant academic research and scientific papers

Isolation and structure elucidation of vicenistatin M, and importance of the vicenisamine aminosugar for exerting cytotoxicity of vicenistatin

A new analogue of vicenistatin was isolated from the producing strain Streptomyces sp. HC-34. A characteristic of the elucidated structure involved the existence of a neutral sugar mycarose instead of an aminosugar vicenisamine of vicenistatin. The absolu

An Improved Procedure for the Ring Opening of Benzylidene Acetals with N-Bromosuccinimide

A new procedure for the ring opening of 4,6-O-benzylidene acetals of carbohydrates with N-bromosuccinimide using calcium carbonate in stoechiometric amount instead of excess barium carbonate is described.This procedure is succesfully applied to some highl

SYNTHESIS OF THE DISACCHARIDE C-D FRAGMENT FOUND IN EVERNINOMICIN-C AND -D, AVALAMYCIN-A AND -C, AND CURAMYCIN-A: STEREOCHEMISTRY AT THE SPIRO-ORTHOLACTONE CENTER

The two isomers at the spiro-ortholactone center of the disaccharide C-D fragment of orthosomycins have been synthesized.Their mild acidic hydrolysis was under stereoelectronic control with each isomer leading to only one ester.It is therefore possible, f

Syntheses and Reactions of 3-C-Methyl-branched Glycals of the D-Series. Preparations of the Isomers of Terminal Disaccharides in Olivomycin A and Mithramycin

Syntheses of D-olivomycal (6) and D-mycaral (9) are achieved starting with D-rhamnal (4) or D-digitoxal (5), respectively.The transformation of 9 to methyl α-D-mycaroside (12) represents a configurational assignment at the branching point.With methyllithi

Synthesen biologisch wichtiger Kohlenhydrate, 24. Derivate des Sibirosamins (4,6-Didesoxy-3-C-methyl-4-methylamino-D-altropyranose) durch 4 -> 2-Chiralitaetstransfer und vic. cis-Oxyaminierung eines 3-C-Methyl-hex-3-enopyranosids

Methyl 4-O-benzoyl-2,6-didesoxy-3-C-methyl-α-D-ribo-hexopyranoside (14) yields the D-erythro configurated 3-C-branched hex-2-enopyranosides 15 and 16, resp., with high selectivity by elimination with thionyl chloride. 16 is transformed with complete inver