77-77-0

Basic information

• Product Name: Divinyl sulphone
• Synonyms: tl797;1,1'-sulfonylbisethene;DIVINYL SULPHONE;DIVINYL SULFONE;VINYL SULFONE;VINYL SULPHONE;Vinyl sulfone or divinyl sulfone;VS
• CAS NO: 77-77-0
• Molecular Formula: C₄H₆O₂S
• Molecular Weight: 118.15
• EINECS: 201-057-6
• Product Categories: Sulfur Compounds (for Synthesis);Synthetic Organic Chemistry
• Mol File: 77-77-0.mol
• Article Data: 21

Chemical Properties

• Melting Point: −26 °C(lit.)
• Boiling Point: 234 °C(lit.)
• Flash Point: 217 °F
• Appearance: /liquid
• Density: 1.177 g/mL at 25 °C(lit.)
• Vapor Pressure: 0.0805mmHg at 25°C
• Refractive Index: n20/D 1.476(lit.)
• Storage Temp.: 2-8°C
• Solubility: Chloroform, DMSO (Sparingly), Ethyl Acetate (Slightly)
• Water Solubility: >=10 g/100 mL at 17 ºC
• Stability: Stable. Incompatible with strong oxidizing agents.
• BRN: 1071329
• CAS DataBase Reference: Divinyl sulphone(CAS DataBase Reference)
• NIST Chemistry Reference: Divinyl sulphone(77-77-0)
• EPA Substance Registry System: Divinyl sulphone(77-77-0)

Safety Data

• Hazard Codes: T+,T,C
• Statements: 25-27-36/37/38-26/27/28-41-37/38
• Safety Statements: 26-28-36/37-45-36/37/39-23
• RIDADR: UN 2810 6.1/PG 1
• WGK Germany: 3
• RTECS: KM7175000
• F: 10
• HazardClass: 6.1
• PackingGroup: I
• Hazardous Substances Data: 77-77-0(Hazardous Substances Data)

Usage

Chemical Properties

colourless liquid

Uses

Divinyl sulfone acts as a cross-linking reagent for agarose gels. It is a monomer, which is used in the production of polymers with diols, urea and malonic esters. Further, it serves as a shrinkage control agent in textiles. In addition to this, it is used in the preparation of large class of fiber-reactive dyestuffs.

Definition

ChEBI: A sulfone compound having two S-vinyl substituents.

General Description

Clear colorless liquid.

Air & Water Reactions

Water soluble.

Reactivity Profile

Divinyl sulphone may react vigorously with strong oxidizing agents. Can react exothermically with reducing agents (such as alkali metals and hydrides) to release gaseous hydrogen or hydrogen sulfide. May react exothermically with both acids and bases. May undergo exothermic polymerization iIn the presence of various catalysts (such as acids) or initiators.

Health Hazard

ACUTE/CHRONIC HAZARDS: Divinyl sulphone may be corrosive.

Fire Hazard

Divinyl sulphone is combustible.

InChI:InChI=1/C4H6O2S/c1-3-7(5,6)4-2/h3-4H,1-2H2

Upstream product

• 627-51-0 divinyl sulfide 
• 471-03-4 bis(2-chloroethyl)sulfone 
• 121-44-8 triethylamine 
• 71-43-2 benzene 
• 7732-18-5 water 
• 3763-72-2 1,1'-Sulphonylbis(2-acetoxyethane) 
• 814-49-3 diethyl chlorophosphate 
• 31469-08-6 ethane-1,2-disulfonyl chloride 
• 3536-96-7 vinylmagnesium chloride 
• 5819-08-9 bis(2-chloroethyl)sulfoxide 
• 64-17-5 ethanol 
• 2580-77-0 sulfonyldiethanol 
• 7327-58-4 1-(2-Chloroethylsulfonyl)ethene 

Downstream Products

• 26475-62-7 4-(2-hydroxyethyl)thiomorpholine 1,1-dioxide 
• 17700-30-0 bis-(2-ethylsulfanyl-ethyl) sulfone 
• 25343-91-3 N-methylthiomorpholine 1,1-dioxide 
• 17700-38-8 (2-Ethenesulfonyl-ethylsulfanyl)-benzene 
• 10442-03-2 4-propargylthiomorpholine-1,1-dioxide 
• 59801-50-2 4-benzhydryl-thiomorpholine 1,1-dioxide 
• 13669-05-1 1,4-bis(thiophen-2-yl)butane-1,4-dione 
• 82222-73-9 4-(2-chlorophenyl)-thiomorpholine 1,1-dioxide 
• 502762-61-0 7,13-dibenzyl-1,4-dioxa-10-thia-7,13-diazacyclopentadecane 10,10-dioxide 

Relevant articles and documents

Example of double elimination in oxidation of a cyclic telluride [10]

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A convenient synthesis of (E)-conjugated polyene sulfonyl derivatives with excellent stereospecificity

A highly selective synthesis of conjugated polyene sulfonyl derivatives is described via the elimination of disulfonyl chloride with readily accessible raw material dihaloalkane. The protocol offers a convenient way to form sulfonamides, sulfonates and even sulfones. Furthermore, this method was manipulated under mild condition with simple operation in high yield to afford only trans products.

Synthesis and characterization of PMoV/Fe3O4/g-C3N4 from melamine: An industrial green nanocatalyst for deep oxidative desulfurization

A facile approach to the preparation of a novel magnetically separable H5PMo10V2O40/Fe3O4/g-C3N4 (PMoV/Fe3O4/g-C3N4) nanocomposite by chemical impregnation is demonstrated. The prepared nanocomposite was characterized and its acidity was measured by potentiometric titration. PMoV/Fe3O4/g-C3N4 showed high catalytic activity in the selective oxidative desulfurization of sulfides to their corresponding sulfoxides or sulfones. The catalytic oxidation of a dibenzothiophene (DBT)-containing model oil and that of real oil were also studied under optimized conditions. In addition, the effects of various nitrogen compounds, as well as the use of one- and two-ring aromatic hydrocarbons as co-solvents, on the catalytic removal of sulfur from DBT were investigated. The catalyst was easily separated and could be recovered from the reaction mixture by using an external magnetic field. Additionally, the remaining reactants could be separated from the products by simple decantation if an appropriate solvent was chosen for the extraction. The advantages of this nanocatalyst are its high catalytic activity and reusability; it can be used at least four times without considerable loss of activity.