31469-08-6Relevant articles and documents
1,2-Ethan-bis-sulfonylfluorid
Haegele, G.,Jueschke, R.,Olschner, R.,Sartori, P.
, p. 61 - 66 (1995)
The synthesis of 1,2-ethane-bissulfonyl fluoride is described. 1H and 19F NMR spectra are analysed and iterated.Novel NMR programs are commented upon. 1,2-Ethane-bis-sulfonyl fluoride favours a trans conformation. - Keywords: Synthesis; 1,2-Ethane-bis-sulfonyl fluoride; NMR spectroscopy; IR spectroscopy; Crystal structure; Mass spectrometry; NMR programs
A convenient synthesis of (E)-conjugated polyene sulfonyl derivatives with excellent stereospecificity
Yu, Chunyan,Lv, Zhongwen,Xu, Sheng,Zhang, Jun
, p. 3234 - 3237 (2018)
A highly selective synthesis of conjugated polyene sulfonyl derivatives is described via the elimination of disulfonyl chloride with readily accessible raw material dihaloalkane. The protocol offers a convenient way to form sulfonamides, sulfonates and even sulfones. Furthermore, this method was manipulated under mild condition with simple operation in high yield to afford only trans products.
Non-aqueous electrolytic solution, electrochemical element using the same and alkynyl compound used therefor
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Paragraph 0185, (2015/07/02)
The present invention provides an excellent nonaqueous electrolytic solution capable of improving low-temperature and high-temperature cycle properties and load characteristics after high-temperature charging storage, an electrochemical element using it, and an alkynyl compound used for it. The nonaqueous electrolytic solution of the present invention comprises at least one alkynyl compound represented by the following general formula (I) in an amount of from 0.01 to 10% by mass in the nonaqueous electrolytic solution. ???????? R1(O)n-X1-R2?????(I) In the formula, X1 represents a group -C(=O)-, a group -S(=O)2-, or a group -P(=O)(-R3)-. R1 represents an alkenyl group having from 2 to 8 carbon atoms; R2 represents an alkynyl group having from 3 to 8 carbon atoms or an alkynyloxy group having from 3 to 8 carbon atoms; R3 represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, an alkoxy group, an alkenyloxy group, an alkynyloxy group, or an aryloxy group; n indicates 0 or 1.
NON-AQUEOUS ELECTROLYTIC SOLUTION, ELECTROCHEMICAL ELEMENT USING SAME, AND ALKYNYL COMPOUND USED THEREFOR
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, (2012/12/13)
The present invention provides an excellent nonaqueous electrolytic solution capable of improving low-temperature and high-temperature cycle properties and load characteristics after high-temperature charging storage, an electrochemical element using it, and an alkynyl compound used for it. The nonaqueous electrolytic solution of the present invention comprises containing at least one alkynyl compound represented by the following general formula (I) in an amount of from 0.01 to 10% by mass in the nonaqueous electrolytic solution. [in-line-formulae]R1(O)n—X1—R2??(I)[/in-line-formulae] (In the formula, X1 represents a group —C(═O)—, a group —C(═O)—C(═O)—, a group —S(═O)2—, a group —P(═O) (—R3)—, or a group —X2—S(═O)2O—. R1 represents an alkenyl group, a formyl group, an alkyl group, an acyl group, an arylcarbonyl, an alkanesulfonyl group, an alkynyloxysulfonyl group, an arylsulfonyl group, a dialkylphosphoryl group, an alkyl(alkoxy)phosphoryl group, or a dialkoxyphosphoryl group; R2 represents an alkynyl group or an alkynyloxy group; R3 represents an alkyl group, an alkenyl group, an alkynyl group, an aryl group, an alkoxy group, an alkenyloxy group, an alkynyloxy group, or an aryloxy group; n indicates 0 or 1.
Synthesis and characterization of N,N′-1,2-ethylenebis(4-methyl phenyl sulfonimide) as a novel sulfonimide
Manesh, Abbas Amini
experimental part, p. 5787 - 5788 (2012/07/13)
In present studied, the synthesis and characterization of N,N′-1,2-ethylene-bis(4-methyl phenyl sulfonimide) is reported.