87228-30-6

Basic information

• Product Name: Benzene, 1-chloro-2,3,5,6-tetrafluoro-4-(trichloromethyl)-
• Synonyms: p-Chloro-o,o,m,m-tetrafluorotrichloromethylbenzene;p-chloro-tetrafluorobenzotrichloride;Benzene,1-chloro-2,3,5,6-tetrafluoro-4-(trichloromethyl);4-chlorotetrafluorobenzotrichloride
• CAS NO: 87228-30-6
• Molecular Formula: C7Cl4F4
• Molecular Weight: 301.883
• Mol File: 87228-30-6.mol

Chemical Properties

• CAS DataBase Reference: Benzene, 1-chloro-2,3,5,6-tetrafluoro-4-(trichloromethyl)-(CAS DataBase Reference)
• NIST Chemistry Reference: Benzene, 1-chloro-2,3,5,6-tetrafluoro-4-(trichloromethyl)-(87228-30-6)
• EPA Substance Registry System: Benzene, 1-chloro-2,3,5,6-tetrafluoro-4-(trichloromethyl)-(87228-30-6)

Safety Data

• Hazardous Substances Data: 87228-30-6(Hazardous Substances Data)

Upstream product

• 56-23-5 tetrachloromethane 
• 363-72-4 Pentafluorobenzene 
• 778-34-7 1,2,3,4,5-pentafluoro-6-(trichloromethyl)benzene 
• 434-64-0 perfluorotoluene 
• 828-73-9 pentafluorophenyl hydrazine 

Downstream Products

• 101306-34-7 4-chloro-α-chlorohexafluorostyrene 
• 128100-05-0 Bis(p-chlorotetrafluorophenyl)dichloromethane 
• 1198-62-5 1,4-dichloro-2,3,5,6-tetrafluorobenzene 
• 5211-45-0 4-chloro 2,3,5,6-tetrafluoro benzoic acid 
• 136264-75-0 p-chlorotetrafluorobenzotribromide 
• 169781-24-2 4-(α,α,β-trichlorodifluoroethyl)chlorotetrafluorobenzene 
• 169781-22-0 4-chlorodifluoromethyl-α-chlorohexafluorostyrene 
• 60903-82-4 4-chloro-2,3,5,6-tetrafluorotoluene 
• 5230-78-4 2,3,5,6-tetrafluorotoluene 

Relevant articles and documents

Selective hydrolysis of pentafluorobenzotrichloride

Selective hydrolysis of pentafluorobenzotrichloride has been studied in the presence of a catalytic amount of iron(III) chloride. The main products are pentafluorobenzoyl chloride, pentafluorobenzoyl fluoride, and 4-chlorotetrafluorobenzoyl chloride. The two latter products are formed by hydrolysis of dichlorofluoromethylpentafluorobenzene and 4- chlorotetrafluorobenzotrichloride which result from halogen exchange between the methyl group and aromatic ring in the initial pentafluorobenzotrichloride. A probable mechanism for halogen exchange is proposed.

PREPARATION OF POLYFLUOROBENZOTRIHALIDES BY THE REACTIONS OF OCTAFLUOROTOLUENE AND ITS DERIVATIVES WITH ALUMINUM HALIDES. SYNTHESIS OF POLYFLUOROSTILBENES AND DECAFLUOROTOLAN

Reactions of some polyfluoro aromatic compounds containing a CF3 group with aluminum halides (AlCl3, AlBr3) were studied.In these reactions there occurs the replacement of fluorine atoms by chlorine or bromine both in the side chain in aromatic ring.Treat

FORMATION OF POLYFLUOROTRICHLOROMETHYLBENZENES FROM PENTAFLUOROBENZENE AND CCl4 IN THE PRESENCE OF AlCl3

The reaction of pentafluorobenzene with CCl4 in the presence of AlCl3 gives p-chloro-o,o,m,m-tetrafluorotrichloromethylbenzene as the major product along with pentafluorotrichloromethylbenzene and bis(p-chlorotetrafluorophenyl)dichloromethane.

REACTIONS OF PENTAFLUOROPHENYLHYDRAZINE AND SOME OF ITS N'-ACYL DERIVATIVES WITH COMPOUNDS CONTAINING A TRICHLOROMETHYL GROUP IN THE PRESENCE OF ALUMUNIUM CHLORIDE

The reactions of pentafluorophenylhydrazine and also of N'-benzoyl-, N'-pentafluorobenzoyl-, and N'-acetylpentafluorophenylhydrazines and decafluorohydrazobenzene with CCl3R (R=Cl, C6H5, C6F5) in the presence of aluminium chloride were investigated.The main products from the reaction of pentafluorophenylhydrazine with the reagents were N-pentafluorophenylhydrazonodichloromethane and N-pentafluorophenylhydrazonoaryl chlorides.Derivatives of 1,3,4-oxadiazol-2-in-5-one were formed in the reactions of N'-acylpentafluorophenylhydrazines with carbon tetrachloride in the pres ence of aluminium chloride.When heated with carbon tetrachloride and aluminium chloride, decafluorohydrazobenzene disproportionates with the formation of decafluoroazobenzene and pentafluoroaniline.