89827-45-2

Basic information

• Product Name: 4-BROMODIBENZOFURAN
• Synonyms: 4-BROMODIBENZOFURAN;4-Bromodibenzo[b,d]furan;Dibenzofuran, 4-bromo-
• CAS NO: 89827-45-2
• Molecular Formula: C₁₂H₇BrO
• Molecular Weight: 247.08738
• Mol File: 89827-45-2.mol

Chemical Properties

• Melting Point: 67-69℃
• Boiling Point: 220 °C(Press: 40 Torr)
• Appearance: /
• Density: 1.577
• Storage Temp.: Sealed in dry,Room Temperature
• CAS DataBase Reference: 4-BROMODIBENZOFURAN(CAS DataBase Reference)
• NIST Chemistry Reference: 4-BROMODIBENZOFURAN(89827-45-2)
• EPA Substance Registry System: 4-BROMODIBENZOFURAN(89827-45-2)

Safety Data

• Hazard Codes: Xn
• Statements: 22-36-53
• Safety Statements: 26
• WGK Germany: 3
• Hazardous Substances Data: 89827-45-2(Hazardous Substances Data)

Usage

Uses

Used in Semiconductor Industry:
4-BROMODIBENZOFURAN is used as a chemical precursor for the synthesis of 4-substituted dibenzofuranes, which are valuable components in the development of semiconductor materials. These materials contribute to the advancement of electronic devices and systems.
Used in OLED Applications:
In the field of organic light-emitting diodes (OLEDs), 4-BROMODIBENZOFURAN is utilized as a key intermediate for the production of 4-substituted dibenzofuranes. These compounds are essential for creating efficient and high-performing OLED materials, which are used in display technologies and lighting applications.

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Downstream Products

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• 151832-13-2 5-(1,1-dimethylethyl)-3-(chloromethyl)-3-(hydroxymethyl)-2,2',2,2',2-pentamethoxy-<1,1':3',1:3,1':3',1-quinquephenyl> 
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• 127799-22-8 dimethyl 5-(1,1-dimethylethyl)-2,2',2,2',2-pentamethoxy<1,1':3',1:3,1':3',1-quinquephenyl>-3,3-dicarboxylate 
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• 100124-06-9 4-dibenzofurylboronic acid 
• 916435-45-5 6-bromo-2-iododibenzo[b,d]furan 

Relevant articles and documents

Direct bromodeboronation of arylboronic acids with CuBr2 in water

An efficient and practical method has been developed for the preparation of aryl bromides via the direct bromodeboronation of arylboronic acids with CuBr2 in water. This strategy provides several advantages, such as being ligand-free, base-free, high yielding, and functional group tolerant.

Compound, electronic element and electronic device

The invention provides a compound, an electronic component and an electronic device, and relates to the technical field of organic materials, wherein the compound is represented by a formula I, X1, X2and X3 are the same or different and are respectively and independently selected from carbon and nitrogen, X1, X2 and X3 are not carbon at the same time, L is selected from a single bond, arylene, heteroarylene, aryl alkylene and heteroaryl alkylene, Ar1 is selected from alkyl, cycloalkyl, aryl, heteroaryl, alkoxy, alkylamino, arylamino and arylalkylamino, and Ar2 and Ar3 are the same or different and are respectively and independently selected from cycloalkyl, aryl, heteroaryl, alkoxy, alkylamino, arylamino and arylalkylamino. The compound provided by the invention can reduce the working voltage of an electronic component, improve the luminous efficiency of the electronic component and prolong the service life of a device.

Regioselective arene homologation through rhenium-catalyzed deoxygenative aromatization of 7-oxabicyclo[2.2.1]hepta-2,5-dienes

Combined use of oxorhenium catalysts with triphenyl phosphite as an oxygen acceptor allowed efficient deoxygenative aromatization of oxabicyclic dienes. The reaction proceeded under neutral conditions and was compatible with various functional groups. Combining this deoxygenation with regioselective bromination and trapping of the generated aryne with furan resulted in benzannulative π-extension at the periphery of the PAHs. This enabled direct use of unfunctionalized PAHs for extension of π-conjugation. Iteration of the transformations increased the number of fused-benzene rings one at a time, which has the potential to alter the properties of PAHs by fine-tuning the degree of π-conjugation, shape, and edge topology.

COMPOUND FOR ORGANIC ELECTRIC ELEMENT, ORGANIC ELECTRIC ELEMENT COMPRISING THE SAME AND ELECTRONIC DEVICE THEREOF

Provided are a compound represented by Formula 1, and an organic electric element comprising a first electrode, a second electrode, and an organic material layer formed between the first electrode and the second electrode, wherein the organic material layer comprised the compound represented by Formula 1, and the driving voltage of an organic electronic device can be lowered, and the luminous efficiency, color purity and life time of an organic electronic device can be improved by comprising the compound represented by Formula 1 in the organic material layer.

AROMATIC HETEROCYCLIC DERIVATIVE, AND ORGANIC ELECTROLUMINESCENT ELEMENT, ILLUMINATION DEVICE, AND DISPLAY DEVICE USING AROMATIC HETEROCYCLIC DERIVATIVE

The present invention addresses the problem of providing a novel aromatic heterocyclic derivative, providing an organic EL element that uses the derivative and has high luminous efficiency, long luminescence life, and few changes over time when used under high temperatures, and providing a display device and an illumination device that are equipped with the organic El element. This aromatic heterocyclic derivative is characterized by having a specific structure which includes a carbazole ring.

Visible-Light-Promoted Synthesis of Dibenzofuran Derivatives

Dibenzofurans are naturally occurring molecules that have received considerable attention for a variety of practical applications, such as in pharmaceuticals and electronic materials. Herein, an efficient and eco-friendly method for the synthesis of dibenzofuran derivatives via intramolecular C-O bond formation, which involves the in situ production of a diazonium salt, is described. The transformation requires a diazotizing agent and is promoted by the use of an organic photosensitizer under visible-light irradiation.

COMPOUND FOR ORGANIC ELECTRIC ELEMENT, ORGANIC ELECTRIC ELEMENT COMPRISING THE SAME AND ELECTRONIC DEVICE THEREOF

Provided is a compound which is represented by chemical formula 1. Also, provided is an organic electrical device which comprises: a first electrode; a second electrode; and an organic material layer between the first electrode and the second electrode. The organic material layer includes the compound represented by chemical formula 1. When the compound represented by chemical formula 1 is contained in the organic material layer of the organic electrical device, driving voltage decreases, while luminous efficiency, color purity, and lifespan increase.COPYRIGHT KIPO 2017

NOVEL ORGANIC COMPOUND, MATERIAL COMPRISING THE SAME FOR ORGANIC ELECTROLUMINESCENCE DEVICES, AND ORGANIC ELECTROLUMINESCENCE DEVICE COMPRISING THE MATERIAL

The present invention provides a novel organic compound of General Formula 1, a material comprising the same for organic electroluminescence devices, and an organic electroluminescence device comprising the material. The organic compound of the present invention is useful in organic electroluminescence devices as a hole injection layer substance, a hole transport layer substance, an electron blocking layer substance, and an emission layer substance such as green and red phosphorescent host substance, and when used in the organic electroluminescence devices, can reduce the drive voltage, and increase the luminous efficiency, luminance, thermal stability, color purity and service life of the devices.

NOVEL ORGANIC COMPOUND, MATERIAL COMPRISING THE SAME FOR ORGANIC ELECTROLUMINESCENCE DEVICES, AND ORGANIC ELECTROLUMINESCENCE DEVICE COMPRISING THE MATERIAL

The present invention provides a novel organic compound, a material comprising the same for organic electroluminescence devices, and an organic electroluminescence device comprising the material. The organic compound provided in the present invention is useful in organic electroluminescence devices as a hole injection layer material, a hole transport layer material, an electron blocking layer material, and an emission layer material such as green and red phosphorescent host material, and can reduce the drive voltage, and increase the luminous efficiency, luminance, thermal stability, color purity and service life of the devices.

C∧C Cyclometalated Platinum(II) Complexes with Dibenzofuranyl-1,2,4-triazol-5-ylidene Ligands: Synthesis, Characterization, and Photoluminescent Properties

Two series of new platinum(II) NHC complexes with C∧C cyclometalating 1-(dibenzo[b,d]furan-4-yl)-4-methyl-1H-1,2,4-triazole and 1-(dibenzo[b,d]furan-2-yl)-4-methyl-1H-1,2,4-triazole ligands and several β-diketonato auxiliary ligands (acetylacetonato, dibenzoylmethanato, and dimesitoylmethanato) were synthesized, characterized (NMR spectroscopy, elemental analysis, and X-ray crystallography for two complexes) and investigated in terms of their photoluminescence properties. All complexes are strongly emissive at room temperature in a 2 wt % complex doped poly(methyl methacrylate) film at room temperature. Using dibenzoylmethanato as auxiliary ligand leads to a broad emssion band with a maximum in the green region of the spectrum, whereas the complexes with acetylacetonato and dimesitoylmethanato ligands reveal structured blue emissions with wavelengths that strongly depend on the arrangement of the dibenzo[b,d]furan (DBF) unit.