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Cas Database |
| Name |
Cylopropylmethyl chloride |
EINECS | 227-632-1 |
| CAS No. | 5911-08-0 | Density | 1.056 g/cm3 |
| PSA | 0.00000 | LogP | 1.63520 |
| Solubility | Not miscible in water. | Melting Point |
-91 °C |
| Formula | C4H7Cl | Boiling Point | 87.6 °C at 760 mmHg |
| Molecular Weight | 90.5526 | Flash Point | 29 °F |
| Transport Information | UN 1993 3/PG 2 | Appearance | COA |
| Safety | 16-26-36/37/39 | Risk Codes | 11-36/37/38 |
| Molecular Structure |
|
Hazard Symbols |
 F,  Xi
|
| Synonyms |
(Chloromethyl)cyclopropane;Chlorocyclopropylmethane;Cyclopropanemethyl chloride;Cyclopropylcarbinylchloride;Cyclopropylchloromethane;a-(Chloromethyl)cyclopropane; |
Article Data | 35 |
Cylopropylmethyl chloride Synthetic route
| Conditions | Yield |
|---|---|
| With phenylphosphorus tetrachloride In chloroform at 0℃; for 0.0833333h; | 98% |
| With 1,1,1,3,3,3-hexachloro-propan-2-one; triphenylphosphine at 0 - 20℃; for 3.25h; | 95% |
| With 1,3,5-trichloro-2,4,6-triazine In acetonitrile at -10 - 25℃; for 5h; Solvent; Temperature; | 94% |
- 56-23-5
tetrachloromethane
- 112057-32-6
tri(cyclopropylmethyl)phosphite
A
- 927-73-1
3-butenyl chloride
B
- 27301-78-6
Phosphoric acid tricyclopropylmethyl ester
C
- 112142-26-4
Trichloromethyl-phosphonic acid dicyclopropylmethyl ester
D
- 5911-08-0
chloro(cyclopropyl)methane
| Conditions | Yield |
|---|---|
| In toluene at 80℃; Further byproducts given; | A 16% B 2% C 80% D 64% |
- 2516-33-8
Cyclopropylmethanol
A
- 927-73-1
3-butenyl chloride
B
- 1120-57-6
chlorocyclobutane
C
- 5911-08-0
chloro(cyclopropyl)methane
| Conditions | Yield |
|---|---|
| A 15% B 18% C 80% |
- 2154-76-9
cyclopropylmethyl
A
- 927-73-1
3-butenyl chloride
B
- 1190-22-3
1,3-dichlorobutane
C
- 1790-22-3
1,2,4-trichlorobutane
D
- 5911-08-0
chloro(cyclopropyl)methane
| Conditions | Yield |
|---|---|
| With chlorine In benzene Rate constant; Product distribution; Irradiation; other chlorinating agents; | A 10.3% B 6.2% C 19.1% D 34.4% |
- 594-11-6
methylcyclopropane
A
- 927-73-1
3-butenyl chloride
B
- 1190-22-3
1,3-dichlorobutane
C
- 1790-22-3
1,2,4-trichlorobutane
D
- 5911-08-0
chloro(cyclopropyl)methane
| Conditions | Yield |
|---|---|
| With chlorine In 1,1,2-Trichloro-1,2,2-trifluoroethane at 20℃; Irradiation; | A 10.3% B 6.2% C 19.1% D 34.4% |
| With tert-butylhypochlorite In 1,1,2-Trichloro-1,2,2-trifluoroethane at 20℃; for 2.5h; Irradiation; | A 17% B 3.2% C 6.5% D 24.2% |
| Conditions | Yield |
|---|---|
| With phosphorus pentachloride | |
| With hydrogenchloride |
| Conditions | Yield |
|---|---|
| With chlorine Irradiation; | |
| With chlorine at -196.1℃; Quantum yield; Irradiation; var. magnetic field; |
- 1120-57-6
chlorocyclobutane
- 127-08-2
potassium acetate
- 64-19-7
acetic acid
- 5911-08-0
chloro(cyclopropyl)methane
| Conditions | Yield |
|---|---|
| at 100℃; Rate constant; Solvolyse und Isomerisierung; |
| Conditions | Yield |
|---|---|
| Cu catalyst |
- 310447-99-5, 310448-01-2
3,4-dichlorobut-1-ene
- 5911-08-0
chloro(cyclopropyl)methane
| Conditions | Yield |
|---|---|
| (i) 9-bora-bicyclo<3.3.1>nonane, THF, (ii) aq. NaOH; Multistep reaction; |
Cylopropylmethyl chloride Chemical Properties
IUPAC Name:chloromethylcyclopropane
Molecular Formula:C4H7Cl
Molecular Weight:90.551380 g/mol
Appearance:colorless liquid
Melting Point:-91°C
Boiling Point:87-89 °C(lit.)
Flash Point:29 °F
Water Solubility:1165 mg/L at 25 °C
Density:0.98 g/mL at 25 °C(lit.)
Refractive index:n20/D 1.435(lit.)
BRN:635697
EINECS:227-632-1
Synonyms of Cylopropylmethyl chloride(5911-08-0):
CYCLOPROPYLMETHYL CHLORIDE;(CHLOROMETHYL)CYCLOPROPANE;Cyclopropane, (chloromethyl)-;Cyclopropane,(chloromethyl);Cylopropylmethylchloride;Cyclopropylmethychloride;Cyclopropylmethyl Chloride, Pract.;CPMCl
Categories of Cylopropylmethyl chloride(5911-08-0):
Cycloalkanes;Alkyl;Halogenated Hydrocarbons;Organic Building Blocks
Cylopropylmethyl chloride Safety Profile
Hazard Codes:F
,Xi 
Risk Statements:11-36/37/38
11:Highly Flammable
36/37/38:Irritating to eyes, respiratory system and skin
Safety Statements:16-26-36/37/39
16:Keep away from sources of ignition - No smoking
26:In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39:Wear suitable protective clothing, gloves and eye/face protection
RIDADR:UN 1993 3/PG 2
WGK Germany:3
HazardClass:3
PackingGroup:II
HS Code:29035990
Cylopropylmethyl chloride Specification
First Aid Measures of Cylopropylmethyl chloride(5911-08-0):
Ingestion:If victim is conscious and alert, give 2-4 cupfuls of milk or water. Get medical aid immediately. Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
Inhalation:Get medical aid immediately. Remove from exposure to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen.
Skin:Get medical aid. Flush skin with plenty of soap and water for at least 15 minutes while removing contaminated clothing and shoes. Remove contaminated clothing and shoes.
Eyes:Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid immediately.
Storage of Cylopropylmethyl chloride(5911-08-0):
Keep away from heat, sparks, and flame. Flammables-area.
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