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Cas Database |
| Name |
Dibenzyl peroxydicarbonate |
EINECS | N/A |
| CAS No. | 2144-45-8 | Density | 1.282g/cm3 |
| PSA | 71.06000 | LogP | 3.60820 |
| Solubility | N/A | Melting Point |
101 °C (decomp) |
| Formula | C16H14 O6 | Boiling Point | 403.1°Cat760mmHg |
| Molecular Weight | 302.284 | Flash Point | 177.5°C |
| Transport Information | N/A | Appearance | N/A |
| Safety | An unstable peroxide forbidden for transport. When heated to decomposition it emits acrid smoke and irritating vapors. | Risk Codes | N/A |
| Molecular Structure |
|
Hazard Symbols | N/A |
| Synonyms |
Peroxydicarbonicacid, bis(phenylmethyl) ester (9CI); Peroxydicarbonic acid, dibenzyl ester(6CI,7CI,8CI); Dibenzyl peroxydicarbonate |
Article Data | 5 |
Dibenzyl peroxydicarbonate Chemical Properties
IUPAC Name: Benzyl benzylperoxycarbonyl carbonate
Synonyms of Dibenzyl peroxydicarbonate (CAS NO.2144-45-8) : Bisbenzyl peroxydicarbonate;Peroxydicarbonic acid, bis(phenylmethyl) ester
CAS NO: 2144-45-8
Molecular Formula:C16H14O6
Molecular Weight :302.27876
Molecular Structure :
EINECS: 218-406-3
Index of Refraction:1.563
Surface Tension: 49.2 dyne/cm
Density: 1.282 g/cm3
Flash Point: 177.5 °C
Enthalpy of Vaporization: 65.44 kJ/mol
Boiling Point: 403.1 °C at 760 mmHg
Vapour Pressure: 1.04E-06 mmHg at 25°C
Dibenzyl peroxydicarbonate Uses
Dibenzyl peroxydicarbonate (CAS NO.2144-45-8) is used as intermediate in organic synthesis.
Dibenzyl peroxydicarbonate Safety Profile
An unstable peroxide forbidden for transport. When heated to decomposition it emits acrid smoke and irritating vapors.
RIDADR 3114
HazardClass 5.2
PackingGroup II
Dibenzyl peroxydicarbonate Standards and Recommendations
DOT Classification: Forbidden
Dibenzyl peroxydicarbonate Specification
1.General Description : Dibenzyl peroxydicarbonate (CAS NO.2144-45-8) (not more than 87%,with water) is sensitive to heat. Storage of Diphenylmethyl peroxydicarbonate(not more than 87%,with water) must be done so with stringent temperature control measures. Its explosion hazard is also mitigated by mixing the peroxide in a water slurry.
2.Reactivity Profile :Diphenylmethyl peroxydicarbonate(not more than 87%,with water) decomposes violently or explosively at temperatures 0-10° C. owing to self-accelerating exothermic decomposition; Several explosions were due to shock, heat or friction; amines and certain metals can cause accelerated decomposition [Bretherick, 1979 p. 156]. Danger of explosion when dry
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