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Fenvalerate

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Name

Fenvalerate

EINECS 257-326-3
CAS No. 51630-58-1 Density 1.21 g/cm3
PSA 59.32000 LogP 6.67998
Solubility Soluble in 100% ethanol (>25 mg/ml), water (0.001 g/L) at 20°C, and DMSO. Melting Point N/A
Formula C25H22ClNO3 Boiling Point 538.9 °C at 760 mmHg
Molecular Weight 419.908 Flash Point 279.7 °C
Transport Information UN 2811 6.1/PG 3 Appearance clear viscious yellow liquid
Safety 26-45-60-61 Risk Codes 25-36/37/38-50/53-57
Molecular Structure Molecular Structure of 51630-58-1 (Fenvalerate) Hazard Symbols ToxicT, DangerousN
Synonyms

Sumicidin;Sumitick;Sumifleece;Benzeneacetic acid, 4-chloro-alpha-(1-methylethyl)-, cyano(3-phenoxyphenyl)methyl ester;Sumipower;(RS)-alpha-Cyano-3-phenoxybenzyl (RS)-2-(4-chlorophenyl)-3-methylbutyrate;Belmark;alpha-Cyano-3-phenoxybenzyl-2-(4-chlorophenyl)-3-methylbutyrate;Fenvalerate [BSI:ISO];Aqmatrine;Phenoxin;Fenoxin;Tirade;Phenvalerate;alpha-Cyano-3-phenoxybenzyl alpha-(4-chlorophenyl)isovalerate;Fenusa pusillaBirch leaf miner is also indexed at this headingFenval;Insectral;Fenkem;Sanmarton;Sumkidin;Benzeneacetic acid,4-chloro-R-(1-methylethyl)- ,cyano(3-phenoxyphenyl)methyl ester;alpha-Cyano-3-phenoxybenzyl alpha-isopropyl-4-chlorophenylacetate;Sumibac;Ectrin;Pydrin;Cyano(3-phenoxybenzyl)methyl 2-(4-chlorophenyl)-3-methylbutyrate;Tribute;(+)-alpha-Cyano-3-phenoxybenzyl-(+)-alpha-(4-chlorophenyl)isovalerate;Fenaxin;4-Chloro-alpha-(1-methylethyl)benzeneacetic acid cyano(3-phenoxyphenyl)methyl ester;Fenval;

Article Data 31

Fenvalerate Chemical Properties

Molecular Structure of Fenvalerate (CAS NO.51630-58-1):
 


IUPAC Name: [cyano-(3-phenoxyphenyl)methyl] 2-(4-chlorophenyl)-3-methylbutanoate
EINECS: 257-326-3 
Empirical Formula: C25H22ClNO3
Molecular Weight: 419.9001
H bond acceptors: 4
H bond donors: 0
Freely Rotating Bonds: 8
Polar Surface Area: 59.32 Å2
Index of Refraction: 1.586
Molar Refractivity: 116.44 cm3
Molar Volume: 346.7 cm3
Surface Tension: 47.3 dyne/cm
Density: 1.21 g/cm3
Flash Point: 279.7 °C
Storage temp: −20°C
Merck: 13,4038
Enthalpy of Vaporization: 81.62 kJ/mol
Boiling Point: 538.9 °C at 760 mmHg
Vapour Pressure: 1.11E-11 mmHg at 25°C
Product Categories: Agro-Chemicals; Insecticide
InChI
InChI=1/C25H22ClNO3/c1-17(2)24(18-11-13-20(26)14-12-18)25(28)30-23(16-27)19-7-6-10-22(15-19)29-21-8-4-3-5-9-21/h3-15,17,23-24H,1-2H3
Smiles
c1([C@@H](C(O[C@@H](c2cc(Oc3ccccc3)ccc2)C#N)=O)C(C)C)ccc(Cl)cc1

Fenvalerate Toxicity Data With Reference

1.    

cyt-hmn:lym 2 mg/L

    MUTAEX    Mutagenesis. 4 (1989),72.
2.    

sce-hmn:lym 10 mg/L

    MUTAEX    Mutagenesis. 4 (1989),72.
3.    

orl-rat LD50:70,200 µg/kg

    CHYCDW    Zhonghua Yufangyixue Zazhi. Chinese Journal of Preventive Medicine. 21 (1987),215.
4.    

ivn-rat LDLo:50 mg/kg

    ARTODN    Archives of Toxicology. 45 (1980),325.
5.    

orl-mus LD50:185 mg/kg

    FAATDF    Fundamental and Applied Toxicology. 5 (1985),278.
6.    

ice-mus LDLo:200 µg/kg

    TXAPA9    Toxicology and Applied Pharmacology. 66 (1982),290.
7.    

skn-rbt LD50:2500 mg/kg

    FMCHA2    Farm Chemicals Handbook .(Meister Publishing,Willoughy, OH.: )1983,C104.

Fenvalerate Consensus Reports

Cyanide and its compounds are on the Community Right-To-Know List.

Fenvalerate Safety Profile

Poison by ingestion, intravenous, and intracerebral routes. Moderately toxic by skin contact. Experimental reproductive effects. Mutation data reported. Highly toxic to fish and bees. Corrosive, causes eye damage. A skin irritant. When heated to decomposition it emits toxic fumes of Cl, NOx, and CN. See also CYANIDE.
Hazard Codes: ToxicT,DangerousN
Risk Statements: 25-36/37/38-50/53-57
R25 :Toxic if swallowed. 
R36/37/38:Irritating to eyes, respiratory system and skin. 
R50/53:Very toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R57:Toxic to bees.
Safety Statements: 26-45-60-61
S26: In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. 
S45:In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.) 
S60:This material and its container must be disposed of as hazardous waste. 
S61:Avoid release to the environment. Refer to special instructions / safety data sheets.
RIDADR: UN 2811 6.1/PG 3
WGK Germany: 3
RTECS: CY1576350
HazardClass: 6.1(b)
PackingGroup: III

Fenvalerate Specification

 Fenvalerate , with CAS number of 51630-58-1, can be called Cyano (3-phenoxybenzyl)-2-(4-chlorophenyl)-3-methylbutyrate ; 4-Chloro-alpha-(1-methylethyl)benzeneacetic acid cyano(3-phenoxyphenyl)methyl ester ; Cyano-(3-phenoxyphenyl)methyl 4-chloro-alpha-(1-methylethyl)benzene acetate ; Belmark ; Ectrin ; Extrin ; Fenkill ; Phenvalerate; Pydrin ; Sumicidin; Sumicide; Sumifly ; Sumipower ; Sumitox . Fenvalerate does not affect plants, but is active for an extended period of time. Fenvalerate is an insecticide, against a wide range of pests. It is most commonly used to control insects in food, feed and cotton products, for the control of flies and ticks in barns and stables. Fenvalerate is an insecticide of moderate mammalian toxicity. It is most toxic to bees and fish.

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