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Formylhydrazine

  • Name Formylhydrazine
  • EINECS210-867-9
  • CAS No. 624-84-0
  • Density1.094 g/cm3
  • PSA55.12000
  • LogP0.33320
  • SolubilitySoluble in water
  • Melting Point52-57 °C(lit.)
  • FormulaCH4N2O
  • Boiling Point129.7 °C at 760 mmHg
  • Molecular Weight60.0556
  • Flash Point32.2 °C
  • Transport InformationN/A
  • Appearancewhite shiny crystalline flakes
  • Safety26-36-36/37/39
  • Risk Codes36/37/38-20/21/22
  • Molecular Structure
    Molecular Structure of 624-84-0 (Formylhydrazine)
  • Hazard SymbolsHarmfulXn,IrritantXi
  • SynonymsHarmfulXn,IrritantXi
  • Article Data32

Formylhydrazine Chemical Properties

IUPAC Name: Formohydrazide
The MF of Formohydrazide (CAS NO.624-84-0) is CH4N2O.

                          
The MW of Formohydrazide (CAS NO.624-84-0) is 60.06.
Synonyms of Formohydrazide (CAS NO.624-84-0): Formic hydrazide ; Hydrazine, formyl- ; Formic acid hydrazide ; Carbazaldehyde ; Formhydrazid
Apperance: white shiny crystalline flakes
Index of Refraction: 1.424 
EINECS: 210-867-9
Density: 1.094 g/ml 
Flash Point: 32.2 °C 
Boiling Point: 129.7 °C
Melting Point: 54-56 °C
Storage temp: 2-8 °C
Water Solubility: Soluble
Sensitive: Hygroscopic
BRN: 635759

Formylhydrazine Uses

  Formohydrazide (CAS NO.624-84-0) is used in organic synthesis.

Formylhydrazine Production

Be careful to join the 85% hydrazine hydrate and 95% ethyl alcohol solution,stirring 10min. When the relaxation response,making the reaction solution refluxed 18h, vacuuming steam out of most of the water and ethanol.It was tilting crude syrup, and further refined to be finished formyl hydrazine.

Formylhydrazine Toxicity Data With Reference

1.    

scu-rat LD50:120 mg/kg

    ARZNAD    Arzneimittel-Forschung. Drug Research. 18 (1968),645.
2.    

ipr-mus LD50:65 mg/kg

    JMPCAS    Journal of Medicinal and Pharmaceutical Chemistry. 4 (1961),259.

Formylhydrazine Consensus Reports

Reported in EPA TSCA Inventory.

Formylhydrazine Safety Profile

Poison by intraperitoneal and subcutaneous routes. Questionable carcinogen with experimental neoplastigenic data. When heated to decomposition it emits toxic fumes of NOx. See also HYDRAZINE.Safety information of Formohydrazide (CAS NO.624-84-0):
Hazard Codes  IrritantXi,Xn
Risk Statements 
36/37/38 Irritating to eyes, respiratory system and skin
20/21/22 Harmful by inhalation, in contact with skin and if swallowed
Safety Statements 
26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice
36/37/39 Wear suitable protective clothing, gloves and eye/face protection
WGK Germany  3
RTECS  LQ8615000
F  3-8-10

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