Regiospecific Synthesis of β, γ-Unsaturated Ketones from Allylic Alcohols. Claisen Rearrangement of α-Allyloxy Ketone Enol Derivatives

DOI: 10.1021/jo00359a004

Source and publish data:

Journal of Organic Chemistry p. 1393 - 1401 (1986)

Update date:2022-08-04

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Authors:

Kachinsky, Joseph L. C.

Salomon, Robert G.

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Article abstract of DOI:10.1021/jo00359a004

β,γ-Unsaturated ketones are prepared with regiospecific C-C bond formation at the former γ-position of primary, secondary, or tertiary allylic alcohol precursors by a process involving <3.3> sigmatropic Claisen rearrangement of intermediate α-allyloxy ket

Full text of DOI:10.1021/jo00359a004

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