CONFORMATIONAL ANALYSIS OF TRANS-2,3-DIARYLOXY-1,4-DIOXANES. A TOOL FOR DISCRIMINATING BETWEEN STERIC AND ELECTRONIC EFFECTS IN THE POSITION OF THE CONFORMATIONAL EQUILIBRIA OF SUBSTITUTED DIOXANES

DOI: 10.1016/S0040-4020(01)91399-7

Source and publish data:

Tetrahedron p. 3785 - 3789 (1985)

Update date:2022-09-26

Topics:

Authors:

Pericas, Miquel A.

Riera Antoni

Giralt Ernest

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Article abstract of DOI:10.1016/S0040-4020(01)91399-7

The conformation of several trans-2,3-diaryloxy-1,4-dioxanes has been studied using 1H NMR techniques.Trans-2,3-bis(4-nitrophenoxy)-1,4-dioxane and trans-2,3-bis(4-methoxyphenoxy)-1,4-dioxane have been found to be predominantly (<*>98percent) in diaxial c

Full text of DOI:10.1016/S0040-4020(01)91399-7

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