Cationic Cyclopentaannelation: An Efficient Methylenomycin Synthesis

DOI: 10.1021/ja00272a045

Source and publish data:

Journal of the American Chemical Society p. 3438 - 3442 (1986)

Update date:2022-08-04

Topics:

Authors:

Tius, Marcus A.

Astrab, Donald P.

Fauq, Abdul H.

Ousset, Jean-Bernard

Trehan, Sanjay

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Article abstract of DOI:10.1021/ja00272a045

A cationic cyclopentaannelation reaction which was discovered in our laboratories has been used for an extremely short and efficient synthesis of some methylenomycins.Methylenomycin B was prepared in two steps. (+/-)-Desepoxy-4,5-didehydromethylenomycin A

Full text of DOI:10.1021/ja00272a045

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