Tetrahedron Letters p. 4347 - 4348 (1993)
Update date:2022-08-04
Topics:
Fong, Mei C.
Schiesser, Carl H.
Thiohydroxamic esters (3) derived from the O-carboxymethyl oxime derivatives (2) of 2-(benzylseleno)-benzaldehyde (1: R = H), 2-(benzylseleno)acetophenone (1: R = Me) and 2-(benzylseleno)propiophenone (1: R = Et) decompose smoothly, upon irradiation, with the loss of carbon dioxide and formaldehyde to give the 1,2-benzoselenazoles (5). The reaction presumably involves the iminyl radical intermediate (4) which undergoes intramolecular free-radical homolytic substitution at selenium to afford the product (5).
View MoreShanghai Mio Chemical Co., Ltd
Contact:0086 21- 64401188-622
Address:16 Floor NO.2 Jiefang Building, No. 4855 Dushi Road, 201100 Shanghai, P.R.China
Hangzhou Taiyan Trading Co., Ltd(expird)
Contact:+86-13777583958
Address:NO.63, Xingyi Street, Xihu District, Hangzhou, Zhejiang, China
Shenyang NovPharm Technology Co., Ltd.
Contact:.+86-24-24165786
Address:Room 306, Hongjin Mansion, No. 36-1, Wanliutang Rd., Shenhe District, Shenyang, Liaoning, P.R.C.
Contact:+86-22-26358246
Address:601-4-20, Fujiayuan, Tiantai Road, Hebei District, Tianjin, China
Jiangxi Dongbang Pharmaceutical Co., Ltd.
Contact:+86-795-4433603, 4433388
Address:Fengxin Industrial Park, Fengxin County, Jiangxi Province, P.R.C
Doi:10.1021/jm00036a002
(1994)Doi:10.1021/j100387a004
(1990)Doi:10.1016/0277-5387(95)00399-1
(1996)Doi:10.1039/C8SC02277A
(2018)Doi:10.1021/jm950798a
(1996)Doi:10.1016/0040-4020(95)01102-1
(1996)
