Tetrahedron Letters p. 4347 - 4348 (1993)
Update date:2022-08-04
Topics:
Fong, Mei C.
Schiesser, Carl H.
Thiohydroxamic esters (3) derived from the O-carboxymethyl oxime derivatives (2) of 2-(benzylseleno)-benzaldehyde (1: R = H), 2-(benzylseleno)acetophenone (1: R = Me) and 2-(benzylseleno)propiophenone (1: R = Et) decompose smoothly, upon irradiation, with the loss of carbon dioxide and formaldehyde to give the 1,2-benzoselenazoles (5). The reaction presumably involves the iminyl radical intermediate (4) which undergoes intramolecular free-radical homolytic substitution at selenium to afford the product (5).
View MoreContact:+86-25-83719363
Address:106-7 Chunnan Rd, Chunxi Town, Gaochun, Nanjing, China
Contact:86-21-34622192，13917187091，21-34622765
Address:No. 500 Caobao Road Shanghai P.R China
Xi'an Costrong Pharmaceutical Co., Ltd.
Contact:029- 68576496
Address:Room 2004,Shuibao Building,No.190,South Erhuan Rd, Yanta District,Xi'an,Shaan Xi,China
Contact:+86-0512-69209969
Address:Room 317,Lushan Road,Suzhou New District,Jiangsu Province,China.
Tengzhou Runlong Fragrance Co., Ltd.
website:http://www.tzrunlong.com/
Contact:--
Address:No. 78, Fushan Road, Biomedical Industrial Park, Dawu Town, Tengzhou, Shandong, 277514 China
Doi:10.1021/jm00036a002
(1994)Doi:10.1021/j100387a004
(1990)Doi:10.1016/0277-5387(95)00399-1
(1996)Doi:10.1039/C8SC02277A
(2018)Doi:10.1021/jm950798a
(1996)Doi:10.1016/0040-4020(95)01102-1
(1996)
