MONONUCLEAR η3-ALLYLOSMIUM HYDRIDE COMPLEXES AND THE X-RAY CRYSTAL STRUCTURE OF THE SOLVENTO COMPLEX BF4*EtOH

DOI: 10.1016/0022-328X(85)80228-X

Source and publish data:

Journal of Organometallic Chemistry p. 419 - 428 (1985)

Update date:2022-08-03

Topics:

Authors:

Conway, Christopher

Kemmitt, Raymond D. W.

Platt, Andrew W. G.

Russell, David R.

Sherry, Lesley J. S.

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Article abstract of DOI:10.1016/0022-328X(85)80228-X

The osmium(II) hydryde reacts with 2-methylallylmagnesium chloride and allymagnesium chloride to give the air-stable η³-allylosmium hydride complexes 3-CH2CRCH2)(PPh3)2> (R= Me or H).The orientation of the η³-allyl ligand in these complexes has been established by NOE difference spectra.Treatment of 3-CH2CMeCH2)(PPh3)2> with fluoroboric acid in the presence of a ligand L (L= Ph3P or CO) affords the cationic hydride complexes .The crystal structure of *EtOH has been determined.

Full text of DOI:10.1016/0022-328X(85)80228-X

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