Photochemical Ring Contraction of 8-Aza- and 8-Oxa-3,4-diazatricyclo2,6>oct-4-enes

DOI: 10.1039/c39850001769

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1769 - 1770 (1985)

Update date:2022-08-03

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Authors:

Kurita, Jyoji

Sakai, Hiroichi

Tsuchiya, Takashi

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Article abstract of DOI:10.1039/c39850001769

Photolysis of the 8-oxa-3,4-diazatricyclo<5.1.0.0^2,6>oct-4-enes (7) results in a ring transformation to give the 6-formyl-2,3-diazabicyclo<3.1.0>hex-3-enes (9), whereas the 8-aza compounds (8) give the 2-amino-3-cyano-5-azabicyclo<2.1.0>pentane

Full text of DOI:10.1039/c39850001769

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