Base-Induced α-Alkenylation of Ethyl Bromoacetate, Phenacyl Bromide, and Chloroacetonitrile via B-trans -1-Alkenyl-9-borabicyclononanes

DOI: 10.1021/jo00367a039

Source and publish data:

Journal of Organic Chemistry p. 3398 - 3400 (1986)

Update date:2022-07-31

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Authors:

Brown, Herbert C.

Bhat, Narayan G.

Campbell, James B.

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Article abstract of DOI:10.1021/jo00367a039

B-trans-1-Alkenyl-9-borabicyclo<3.3.1>nonanes, easily and quantitatively prepared by the reaction of 9-BBN with various 1-alkynes in tetrahydrofuran, undergo facile reaction with α-halo carbanions generated from ethyl bromoacetate, phenacyl bromide, and c

Full text of DOI:10.1021/jo00367a039

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