Reaction of a Carbon Equivalent of Iodosylbenzene with Iron-Porphyrins: A Ready Access to N-Alkylporphyrin Complexes Involving Five-Membered Fe-O-C-C-N Metallocycles

Article abstract of DOI:10.1021/ja00278a039

Iron(II)-porphyrin complexes, Fe^IIP (P=tetraarylporphyrin: TPP, TpClPP, and TTP), react with the iodonium ylide C6H5I=X (X=C*C(O)CH2C(CH3)2CH2C*(O)) to give Fe^II-bis-N-alkylporphyrin complexes exhibiting a structure in which the meta