Polyhedron p. 2397 - 2403 (1997)
Update date:2022-09-26
Topics:
Deicas, Bettina
Gambino, Dinorah
Kremer, Carlos
Kremer, Eduardo
Mombru, Alvaro
Suescun, Leopoldo
Mariezcurrena, Raul
Gonzalez, Oscar
Rey, Ana
Mallo, Lourdes
Leon, Alba
Alkylisocyanide complexes of copper(I) with formula [Cu(CNR)4]BF4 [where R = 2-methoxyisobutyl and 2-(carbomethoxy)-2-methylethyl] were synthesized by direct reaction of cuprous chloride with ligand. The stability of solid complexes and their aqueous solutions were tested by HPLC. Comparative studies were carried out on electronic. IR and 1H NMR spectroscopy. Crystal structures of [Cu(MIBI)4]BF4 and [Cu(CPI)4]BF4 were determined from X-ray data and show a tetrahedral arrangement of ligands around the central copper atom in both compounds.
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