Stereoselective Total Synthesis of (+/-)-Invictolide. An Efficient Preparation of a Trisubstituted δ-Lactone from Aldol Precursors

DOI: 10.1021/jo00054a014

Source and publish data:

Journal of Organic Chemistry p. 338 - 342 (1993)

Update date:2022-08-04

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Authors:

Pilli, Ronaldo Aloise

Murta, Maria Marcia

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Article abstract of DOI:10.1021/jo00054a014

The stereoselective total synthesis of (+/-)-invictolide (1), a component of the queen recognition pheromone of Solenopsis invicta, is described.The TiCl4-mediated addition of silyl ketene thioacetal 8 to (+/-)-3-(benzyloxy)-2-methylpropionaldehyde afford

Full text of DOI:10.1021/jo00054a014

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