Tetrahedron Letters p. 7901 - 7904 (1997)
Update date:2022-08-04
Topics:
Kuroda, Yasuhisa
Ueda, Hiroshi
Nozawa, Hiroshi
Ogoshi, Hisanobu
The structures of six peptide mimics having different bulkiness and/or rigidity of the amino acids were investigated spectroscopically. Comparison of H NMR, IR spectra and H-D exchangerate of the amide protons reveals that 2-amino-2-carboxyadamantane induces the high population of γ-turn conformation in the room temperature region and may be utilized as a promising γ-turn inducer for synthetic peptides.
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