Quassinoids. 2. A New Approach to the BCD Ring System

DOI: 10.1021/jo00373a004

Source and publish data:

Journal of Organic Chemistry p. 4347 - 4353 (1986)

Update date:2022-09-26

Topics:

Authors:

Stevens, Robert V.

Angle, Steven R.

Kloc, Ken

Mak, Kok F.

Trueblood, Kenneth N.

Liu, You-Xi

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Article abstract of DOI:10.1021/jo00373a004

Diels-Alder reaction of 2,6-disubstituted quinones 4 and simple dienes 5 furnished cis adducts 3 in good yields.Basic isomerization provided the trans-decalins 11 which were converted into the lactones 2 which are models of the BCD ring systems of quassin

Full text of DOI:10.1021/jo00373a004

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