REACTION OF SILYLKETENE ACETALS WITH 3,3-DIMETHYLACRYLOYL CHLORIDE.

DOI: 10.1016/S0040-4039(00)98989-5

Source and publish data:

Tetrahedron Letters p. 4195 - 4196 (1985)

Update date:2022-07-30

Topics: Reaction Experimental

Authors:

Rousseau, Gerard

Blanco, Luis

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Article abstract of DOI:10.1016/S0040-4039(00)98989-5

The reaction of silylketene acetals with 3,3-dimethylacryloyl chloride in acetonitrile gave γ,δ-ethylenic β-keto esters 3.Application to a new synthesis of (+/-)-turmerone is described.

Full text of DOI:10.1016/S0040-4039(00)98989-5

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