Substituent Effects on Intramolecular Selectivity and Free Energy Relationships in Anodic and Metal Ion Oxidations of 5-X-1,2,3-trimethylbenzenes

DOI: 10.1021/jo00374a010

Source and publish data:

Journal of Organic Chemistry p. 4544 - 4548 (1986)

Update date:2022-07-30

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Authors:

Baciocchi, Enrico

Cort, Antonella Dalla

Eberson, Lennart

Mandolini, Luigi

Rol, Cesare

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Article abstract of DOI:10.1021/jo00374a010

Side-chain oxidations, promoted electrochemically or chemically, by cerium(IV) ammonium nitrate (CAN) or cobalt(III) acetate, of 5-substituted-1,2,3-trimethylbenzenes have been investigated, and the relative reactivity of the 2- and 1-methyl group (k

Full text of DOI:10.1021/jo00374a010

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