Substituent Effects on Intramolecular Selectivity and Free Energy Relationships in Anodic and Metal Ion Oxidations of 5-X-1,2,3-trimethylbenzenes

DOI: 10.1021/jo00374a010

Source and publish data:

Journal of Organic Chemistry p. 4544 - 4548 (1986)

Update date:2022-07-30

Topics:

Authors:

Baciocchi, Enrico

Cort, Antonella Dalla

Eberson, Lennart

Mandolini, Luigi

Rol, Cesare

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1021/jo00374a010

Side-chain oxidations, promoted electrochemically or chemically, by cerium(IV) ammonium nitrate (CAN) or cobalt(III) acetate, of 5-substituted-1,2,3-trimethylbenzenes have been investigated, and the relative reactivity of the 2- and 1-methyl group (k

Full text of DOI:10.1021/jo00374a010

Products guided by the article

Product name:4-carbomethoxy-2,6-dimethylbenzyl acetate

Cas No:104532-03-8

R&D Labs maybe for 104532-03-8

JenKem Technology Co., Ltd.

Contact:86-10-62983737; +86-10-51287608

Address:4/F Building C, 2 Shangdi Xinxi Road
Chinese Peptide Company

Contact:86-571-86737118-8689

Address:No.69, 12 Street, HEDA, Hangzhou, Zhejiang, China
Hunan Dinuo Pharmaceutical Co.,Ltd.

Contact:86-731-88280100*8561

Address:Bio-pharmaceutical industrial park, Liuyang, Hunan, China
Pale Palm Imex

Contact:+36(21)2523420

Address:Head office: 1102 Budapest, SZENT LASZLO TER 24/B. 1/1., HUNGARY / CHINA
KINHENG CHEMICAL(SHANGHAI)CO., LTD.

Contact:+8621-60490170

Address:Room401, No.28,Lane 189, Yangshupu Rd. Shanghai, China.

Relevant to this article

Synthesis of bridgehead-substituted azabicyclo[2.2.1]heptane and -[3.3.1]nonane derivatives for the elaboration of α7 nicotinic ligands

Doi:10.1021/jo201501f
(2011)
ASYMMETRIC ALDOL REACTION OF AMIDE ENOLATES BEARING trans-2,5-DISUBSTITED PYRROLIDINES AS CHIRAL AUXILIARIES

Doi:10.1016/S0040-4039(00)98932-9
(1985)
Oxidant-induced addition reaction of perfluoroalkyl halides to alkenes and alkynes

Doi:10.1016/S0022-1139(97)00132-2
(1998)
Total synthesis of bioactive drimane-epoxyquinol hybrid natural products: Macrophorin A, 4′-oxomacrophorin A, and 1′-epi-craterellin A

Doi:10.1016/j.tetlet.2014.09.075
(2014)
Ru(II)-^PBTNN^XN complex bearing functional 2-(pyridin-2-yl)benzo[d]thiazole ligand catalyzed α-alkylation of nitriles with alcohols

Doi:10.1002/aoc.5451
(2020)
Discovery of 2-[1-(4,4-Difluorocyclohexyl)piperidin-4-yl]-6-fluoro-3-oxo-2,3-dihydro-1H-isoindole-4-carboxamide (NMS-P118): A Potent, Orally Available, and Highly Selective PARP-1 Inhibitor for Cancer Therapy

Doi:10.1021/acs.jmedchem.5b00680
(2015)

Article Doi