Tetrahedron p. 553 - 560 (1986)
Update date:2022-07-30
Topics:
Brinkhaus, Karl-Heinz Grosse
Steckhan, Eberhard
Degner, Dieter
The technically important side-chain oxidation of alkyl aromatic compounds to form either methyl benzoates or orthobenzoic acid trimethylesters can be performed electrochemically at low potentials in methanol solution using an undivided cell and tris(2,4-dibromophenyl)amine as redox catalyst.Under neutral or slightly acidic conditions methyl benzoates are selectively formed while under basic conditions the orthoesters are predominating.In a similar way ortho benzoic acid trimethylesters are formed selectively starting from benzaldehyde dimethylacetals.The redox catalyst is stable under the reaction conditions so that several thousand cycles can be performed without noticeable loss.
View MoreHuixian Tiankai Paper Making Agent CO.,Ltd.
Contact:+86-373-6899808
Address:Mengdian Industrial Avenue,Huixian,Xinxiang,Henan,China
Contact:+36(21)2523420
Address:Head office: 1102 Budapest, SZENT LASZLO TER 24/B. 1/1., HUNGARY / CHINA
WUXI HONOR SHINE CHEMICAL CO.,LTD
Contact:+86-510-83593312
Address:No.1699 Huishan avenue,Huishan district,Wuxi ,Jiangsu,China,214177.(Wuxi Huishan Ecomonic Develop Zone )
YingYing Pharmaceutical Co.,Ltd
Contact:86-18854126208
Address:55#, yingxiongshan road
Contact:+86-515-88356562
Address:No.2, West Daqing Road, Yancheng, Jiangsu, China
Doi:10.1002/chem.19970030409
(1997)Doi:10.1021/ja01136a504
(1952)Doi:10.1021/jp992878m
(1999)Doi:10.1016/0039-128X(90)90010-9
(1990)Doi:10.1055/s-2008-1077825
(2008)Doi:10.1021/jo00376a057
(1986)
