Reactions of 2> with Nitrogen Bases and the Single-crystal X-Ray Structures of i)2>2>H2NCH2CH2NH2 and i)2>2>NC5H5

DOI: 10.1039/DT9860001161

Source and publish data:

Journal of the Chemical Society, Dalton Transactions p. 1161 - 1166 (1986)

Update date:2022-08-04

Topics:

Authors:

Drew, Michael G. B.

Hasan, Masihul

Hobson, Richard J.

Rice, David A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/DT9860001161

The adducts 2>*L i> and the ionic compounds 2 and 2 have been isolated by treating 2> with L in the appropriate stoicheiometry.The crystal structures of i)2>2>*en (1) and i)2>2>*py (2) have been determined: (1), monoclinic, space group P2₁/c, with a=13.402(8), b=16.470(9), c=12.294(7) Angstroem, β=99.0(1) deg, and Z=4; (2), monoclinic, space group P2₁/n with a=21.28(1), b=8.35(1), c=16.27(1) Angstroem, β=99.5(1) deg, and Z=4.Diffractometer data were collected for both crystals and both structures were refined to R 0.073.In (1) the zinc atom is four-co-ordinate forming two Zn-N bonds <2.077(13) and 1.922(16) Angstroem> to the bidentate ethylenediamine molecule and two Zn-S bonds <2.292(5) and 2.331(5) Angstroem> to the monodentate dithiophosphate ligands.In (2) the zinc atom is five-co-ordinate being bonded to pyridine , and to two bidentate dithiophosphate ligands.One ligand is bonded to the metal more symmetrically than the other .The 31P n.m.r. spectra of a number of these compounds have been examined.A correlation between the positions of the resonances and the mode of bonding of the ^- groups to the metal has been established.

Full text of DOI:10.1039/DT9860001161

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:[Zn(S₂P(OC₆H₅)2)2][C₅H₅N]2

Cas No:105237-91-0

R&D Labs maybe for 105237-91-0

Hangzhou jls Flame Retardants Chemical Co.,Ltd

Contact:+86-571-87250387/87250386

Address:MOGANSHAN RODA 1418# SHANGCHENG INDUSTRIAL PARK
Jinhua City Mingzhu Pharmaceutical Co.,Ltd.

Contact:15857995878 0579-82207761

Address:No.169 Shenze Road, New Area,Jinpan Development Zone, Jinhua
Hangzhou Share Chemical Co., Ltd(expird)

Contact:+86-57187093700

Address:Hang Xing Road
Zhengzhou Minzhong Pharmaceutical Co.,ltd

Contact:0086-371-65797115

Address:15/F,Jiangshan Bldg, NO.126 Huanghe Road,Zhengzhou, China
Hangzhou Showland Technology Co., Ltd.

Contact:86-571-88920516

Address:ROOM2118,NO.553,WENSAN ROAD,HANGZHOU,CHINA

Relevant to this article

A NEW ROUTE TO 1-PLATINA-3-SILACYCLOBUTANE

Doi:10.1016/0022-328X(86)84017-7
(1986)
Efficient Synthesis of 4-(3′-Furanyl)butenolide Derivatives via Pd^II-Catalyzed Oxidative Heterodimeric Cyclization Reaction of 2,3-Allenoic Acids and 1,2-Allenyl Ketones

Doi:10.1002/chem.200305341
(2004)
Doi:10.1039/jr9560001103
(1956)
PALLADIUM CATALYZED COUPLING OF F-VINYL ZINC REAGENTS WITH ARYL IODIDES. AN IMPROVED SYNTHESIS OF α,β,β-TRIFLUOROSTYRENES AND THE STEREOSPECIFIC PREPARATION OF 1-PHENYL-F-PROPENES

Doi:10.1016/S0022-1139(00)85092-7
(1986)
6-N-acyltriciribine analogues: Structure - activity relationship between acyl carbon chain length and activity against HIV-1

Doi:10.1021/jm990236h
(2000)
Synthesis of [L-Ala-1]RA-VII, [D-Ala-2]RA-VII, and [D-Ala-4]RA-VII by epimerization of RA-VII, an antitumor bicyclic hexapeptide from rubia plants, through oxazoles

Doi:10.1021/ja021131y
(2003)

Article Doi

Reactions of 2> with Nitrogen Bases and the Single-crystal X-Ray Structures of i)2>2>*H2NCH2CH2NH2 and i)2>2>*NC5H5

DOI: 10.1039/DT9860001161

Source and publish data: