Journal of Organometallic Chemistry p. C35 - C37 (1986)
Update date:2022-08-04
Topics:
Suzuki, Hiroharu
Tsukui, Tatsuyuki
Moro-oka, Yoshihiko
Treatment of chlorobis(trimethylsilyl)methylbis(dimethylphenylphosphine)platinum(II) (1) with t-butyllithium in toluene yields 1,1-bis(dimethylphenylphosphine)-2-trimethylsilyl-3,3-dimethyl-1-platina-3-silacyclobutane (2) via intramolecular nucleophilic attack of the Si-stabilized carbanion or the platinum(II) center.
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