A NEW ROUTE TO 1-PLATINA-3-SILACYCLOBUTANE

DOI: 10.1016/0022-328X(86)84017-7

Source and publish data:

Journal of Organometallic Chemistry p. C35 - C37 (1986)

Update date:2022-08-04

Topics:

Authors:

Suzuki, Hiroharu

Tsukui, Tatsuyuki

Moro-oka, Yoshihiko

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Article abstract of DOI:10.1016/0022-328X(86)84017-7

Treatment of chlorobis(trimethylsilyl)methylbis(dimethylphenylphosphine)platinum(II) (1) with t-butyllithium in toluene yields 1,1-bis(dimethylphenylphosphine)-2-trimethylsilyl-3,3-dimethyl-1-platina-3-silacyclobutane (2) via intramolecular nucleophilic attack of the Si-stabilized carbanion or the platinum(II) center.

Full text of DOI:10.1016/0022-328X(86)84017-7

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