Journal of Organometallic Chemistry p. C51 - C53 (1985)
Update date:2022-07-29
Topics:
McCrindle, Robert
Arsenault, Gilles J.
Farwaha, Rajeev
Reaction of dichloro- and diiodo-(1,5-cyclooctadiene)platinum(II) with excess diazomethane affords the corresponding air-stable bis(halomethyl) complexes Pt(CH2X)2(COD) (X=Cl or I) in excellent yield.Displacement of COD from Pt(CH2Cl)2(COD) with 1,3-bis(diphenylphosphino)propane or two molar equivalents of PPh3 gives the analogous phosphine complexes.
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