THE REACTION OF DICHLORO- AND DIIODO-(1,5-CYCLOOCTADIENE)PLATINUM(II) WITH DIAZOMETHANE. A ROUTE TO BIS(HALOMETHYL)PLATINUM(II) COMPLXES

DOI: 10.1016/0022-328X(85)80384-3

Source and publish data:

Journal of Organometallic Chemistry p. C51 - C53 (1985)

Update date:2022-07-29

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Authors:

McCrindle, Robert

Arsenault, Gilles J.

Farwaha, Rajeev

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Article abstract of DOI:10.1016/0022-328X(85)80384-3

Reaction of dichloro- and diiodo-(1,5-cyclooctadiene)platinum(II) with excess diazomethane affords the corresponding air-stable bis(halomethyl) complexes Pt(CH2X)2(COD) (X=Cl or I) in excellent yield.Displacement of COD from Pt(CH2Cl)2(COD) with 1,3-bis(diphenylphosphino)propane or two molar equivalents of PPh3 gives the analogous phosphine complexes.

Full text of DOI:10.1016/0022-328X(85)80384-3

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