Metal-Free Diaryl Etherification of Tertiary Amines by Ortho-C(sp2)-H Functionalization for Synthesis of Dibenzoxazepines and -ones

DOI: 10.1021/acs.orglett.7b03328

Source and publish data:

Organic Letters p. 6614 - 6617 (2017)

Update date:2022-07-29

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Authors:

Jamsheena, Vellekkatt

Mahesha, Chikkagundagal K.

Joy, M. Nibin

Lankalapalli, Ravi S.

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Article abstract of DOI:10.1021/acs.orglett.7b03328

A phenyliodine(III) diacetate mediated umpolung reactivity of the tertiary amines with suitably substituted o-hydroxybenzyl and phenyl groups is exploited to facilitate o-C(sp²)-H functionalization to afford diaryl ethers. The presence of an o-

Full text of DOI:10.1021/acs.orglett.7b03328

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