Journal of the Chemical Society. Perkin transactions I p. 2915 - 2918 (1996)
Update date:2022-08-04
Topics:
Marais, Charlene
Steenkamp, Jacobus A.
Ferreira, Daneel
The leaves and stems of Aspalathus linear is, a member of the Fabaceae, contains (Z)-2-(β-D-glucopyranosyloxy)-3-phenylpropenoic acid 1, an enolic glucoside of phenylpyruvic acid, representing the first unequivocal evidence for the latter's presence in woody plants. The synthesis of a derivative 2 of the natural product, and of related regiomeric and geometrical isomers 3,4 and 5, and the biosynthetic significance in relation to the shikimic acid pathway are discussed.
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