Journal of the Chemical Society. Chemical communications p. 242 - 244 (1986)
Update date:2022-07-29
Topics:
Tanaka, Jiro
Nojima, Masatomo
Kusabayashi, Shigekazu
The reaction of 1-arylpropenyl-lithium (1a-c) with t-alkyl bromides proceeds by either a nucleophilic substitution or single electron transfer mechanism, the preferred pathway being a function of electronic substituent effects and the absence or presence of tetramethylethylenediamine or hexamethylphosphoramide.
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