STEREOCHEMICAL STUDIES-97. SATURATED HETEROCYCLES-99 AN UNUSUAL RING-OPENING REACTION OF 2-METHYLTHIO-3,1-PERHYDROBENZOXAZINES. A COMPARATIVE STUDY OF THE 3,1 AND 1,3-ISOMERS

DOI: 10.1016/S0040-4020(01)90616-7

Source and publish data:

Tetrahedron p. 2345 - 2350 (1986)

Update date:2022-07-29

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Authors:

Fuoloep, Ferenc

Csirinyi, Gyoergy

Szalma, Sandor

Bernath, Gabor

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Article abstract of DOI:10.1016/S0040-4020(01)90616-7

In the reactions of 2-thioxo-cis and trans-3,1-perhydrobenzoxazines (3,4) with methyl iodide the hydrogen iodide formed in the S-methylation process brings about ring-opening and gives iodomethylthiolcarbamates (7,8).Under similar conditions, the thioethe

Full text of DOI:10.1016/S0040-4020(01)90616-7

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