REGIOSPECIFIC AND STEREOSPECIFIC REACTIONS OF Ph3C + PF6 - WITH RHENIUM ALKYLS ( eta -C5H5)Re(NO)(PPh3)(R). alpha -vs. beta -HYDRIDE ABSTRACTION.

DOI: 10.1021/ja00353a020

Source and publish data:

Journal of the American Chemical Society p. 4958 - 4972 (1983)

Update date:2022-07-29

Topics: Stereospecific Reaction

Authors:

Kiel Kiel

Lin Lin

Bodner Bodner

Gladysz Gladysz

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Article abstract of DOI:10.1021/ja00353a020

This study mapped the structural features which control the regiochemistry of hydride abstraction by Ph//3C** plus PF//6** minus from alkyls eta -C//5H//5)Re(NO)(PPh//3)(R). Accurate predictions can now be made regarding the reactivity of yet unsynthesize

Full text of DOI:10.1021/ja00353a020

Products guided by the article

Product name:{Re(NO)(P(C₆H₅)3)(C₅H₅)(C⁽²⁾H₂C(CH₃)2)}⁽¹⁺⁾*PF₆^(1-)={Re(C₅H₅)(NO)(P(C₆H₅)3)(C⁽²⁾H₂C(CH₃)2)}PF₆

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