Organocatalytic Enantioselective Michael Reaction of Malononitrile with β,β-Disubstituted Nitroalkenes

DOI: 10.1002/adsc.201500079

Source and publish data:

Advanced Synthesis and Catalysis p. 2437 - 2441 (2015)

Update date:2022-08-03

Topics:

Authors:

Chen, Shengwei

Lou, Qinxin

Ding, Yuyang

Zhang, Shasha

Hu, Wenhui

Zhao, Junling

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1002/adsc.201500079

We have developed and optimized an enantioselective Michael reaction of malononitrile with β,β-disubstituted nitroalkenes. This reaction was catalyzed by a cinchona alkaloid derived thiourea catalyst, producing products of high yields (up to 98 %) and ste

Full text of DOI:10.1002/adsc.201500079

Products guided by the article

Product name:tert-butyl 2-hydroxy-3-nitro-2-(4-fluorophenyl)propanoate

Cas No:1070237-31-8

R&D Labs maybe for 1070237-31-8

Ji'an Hairui Natural Plant Co. Ltd.

Contact:0796-8105528

Address:Meilin industry park, Qingyuan district Ji'an City, Jiangxi Province
Wuhan Sunrise Pharmaceutical Technology Co., Ltd

Contact:+86-27-83314682

Address:Room 340, New material Industrial base No.17, Gu Tian Five Lu , Qiaokou District, Wuhan , China
Rizhao Lanxing Chemical Indusrial Co.,Ltd

Contact:86-633-2616708

Address:NO.15 West road Shenglan, Lanshan district, Rizhao City
Shanghai Sharing technologies Co., Ltd.

Contact:86-021-66787223

Address:No11, Lane 225, Jinxiang Road,Pudong district
SHANXI JINJIN CHEMICAL INDUSTRIAL CO.,LTD

website:http://www.jinjingroup.com

Contact:4009982989

Address:Economic And Technological Development Zone,Hejin?City,Shanxi Province?,China

Relevant to this article

Chelating fluorene dyes as mono- and ditopic 2-(1 H -1,2,3-triazol-4-yl) pyridine ligands and their corresponding ruthenium(II) complexes

Doi:10.1055/s-0031-1289771
(2012)
THERMOLYSE DE N,N-DIMETHYL HYDRAZINOPROPENOATES. PREPARATION D'YLURES D'OXOPYRAZOLINIUM ET DE PYRAZOLINONES-5

Doi:10.1016/S0040-4020(01)90606-4
(1986)
Lewis acid catalyzed inverse electron-demand diels-alder reaction of 1,2-diazines

Doi:10.1021/ol101701z
(2010)
Syntheses with N-Trimethylsilylheteroarylium Salts: Reactions with Aldehydes, Ketones and Carboxylic Acids. Comparison of Reactivity with Analogous N-Acylheteroarylium Salts

Doi:10.1055/s-1987-28128
(1987)
Effect of methoxy substituents on the excited state properties of stilbene

Doi:10.1246/bcsj.81.1500
(2008)
CuCI/CCI₄-Promoted Convenient Synthesis of Sulfonyl Amidines from Tertiary Amines and Sulfonyl Azides

Doi:10.1021/ol1000236
(2010)

Article Doi