
Journal of Organometallic Chemistry p. 417 - 422 (1986)
Update date:2022-08-05
Topics:
Oro, L.A.
Carmona, D.
Reyes, J.
Cationic complexes of formula <(C5Me5)Rh(μ-pz)2(μ-CO)Rh(L-L)>BPh4 were prepared by treating a methanolic suspension of <(C5Me5)ClRh(μ-pz)2Rh(CO)2> with NaBPh4 in the presence of the didentate ligands L-L (L-L = bis(diphenylphosphino)methane(dppm), 1,4-bis(diphenylphosphino)butane (dppb), cis-1,2-bis(diphenylphosphino)ethylene (dppen), 1,2-bis(diphenylarsino)ethane (dpae)).The intermediate complex <(C5Me5)Rh(μ-pz)2(μ-CO)Rh(CO)(dppen)>BPh4 was isolated.The formation of the related compounds <(C5Me5)Rh(μ-pz)2(μ-CO)Rh(CO)L>BPh4 (L = PPh3, PCy3) is also reported.
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