Tetrahedron Letters p. 8441 - 8444 (1998)
Update date:2022-08-05
Topics:
Saksena, Anil K.
Jao, Edwin
Murphy, Bruce
Schumacher, Doris
Chan, Tze-Ming
Puar, Mohindar S
Jenkins, John K.
Maloney, Donal
Cordero, Mayra
Pramanik, Birendra N.
Bartner, Peter
Das, Pradip R.
McPhail, Andrew T.
Girijavallabhan
Ganguly, Ashit K.
Degradation of Sch 49088 (1) provided a novel, highly functionalized O- substituted hydroxylamine-containing sugar, everhydroxylaminose 11 isolated as a β-OMe glycoside. Notably the two acid sensitive orthoester moieties in the intact antibiotic 1 co-exist in the presence of three phenolic groups and a free carboxylic acid group.
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