Novel Synthesis of 2-Aminothiophenes via Iodoiminothiolactonization of γ,δ-Unsaturated Secondary Thioamides

DOI: 10.1039/c39860001671

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 1671 (1986)

Update date:2022-08-03

Topics: Characterization Regio-selective Chemo-selective Spectral data Thioamide Synthon Solvent Ring closure Workup and Isolation Reaction Conditions Amino Group Introduction

Authors:

Takahata, Hiroki

Moriyama, Keiko

Moruyama, Mihoko

Yamazaki, Takao

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39860001671

Iodine-induced cyclization of γ,δ-unsaturated secondary thioamides proceeds regio- and chemo-selectively, providing, after elaboration, 2-aminothiophenes.

Full text of DOI:10.1039/c39860001671

View Article Online / Journal Homepage / Table of Contents for this issue

Products guided by the article

Product name:[5-Methylene-dihydro-thiophen-(2E)-ylidene]-phenyl-amine

Cas No:108228-59-7

R&D Labs maybe for 108228-59-7

Chameleon Specialty Chemicals

Contact:+44 7958 511245

Address:PO Box 469, Manchester, UK
Suzhou Sinosun Imp.&Exp. Corporation

website:http://www.szsinosun.com

Contact:+86-512-63488895,63488616

Address:No.758 East Jiangling Road Wujiang Economic & Technological Developmenty Zone Jiangsu China
Zhengzhou HQ Material Co.,Ltd

Contact:+86-371-67759225

Address:No.32, Jinsuo Road, High-tech Zone
Yurui(Shanghai)Chemical Co.,Ltd

Contact:0086 21-50456736

Address:No.3188 Xiupu Road,Shanghai
Shenzhen HwaGen Pharmaceutical Co., Ltd

website:http://www.rafflespt.com

Contact:+86-752-5538396

Address:Guangdong Huizhou China

Relevant to this article

Chemical synthesis of 3-amino-2,3-dideoxy-D-inositol (an intermediate in the biosynthesis of 2-deoxystreptamine) and its D-epi stereoisomers

Doi:10.1016/S0008-6215(00)90119-8
(1986)
Synthesis of 3,5-disubstituted-1,2,4-oxadiazoles using tetrabutylammonium fluoride as a mild and efficient catalyst

Doi:10.1016/S0040-4039(00)02288-7
(2001)
Preparation of imidazolidin-4-ones and their evaluation as hydrolytically cleavable precursors for the slow release of bioactive volatile carbonyl derivatives

Doi:10.1002/ejoc.201200081
(2012)
Synthesis of 2-alkylisoflavones under phase-transfer catalysis conditions

Doi:10.3184/030823407X255533
(2007)
Regioselectivity and Deuterium Isotope Effects in Geraniol Hydroxylation by the Cytochrome P-450 Monooxygenase from Catharanthus roseus (L.) G. Don

Doi:10.1002/hlca.19860690822
(1986)
Doi:10.1039/P19870000251
()

Article Doi