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137-00-8

Basic Information
CAS No.: 137-00-8
Name: 5-(2-Hydroxyethyl)-4-methylthiazole
Article Data: 76
Molecular Structure:
Molecular Structure of 137-00-8 (5-(2-Hydroxyethyl)-4-methylthiazole)
Formula: C6H9NOS
Molecular Weight: 143.21
Synonyms: 5-Thiazoleethanol,4-methyl-;5-(Hydroxyethyl)-4-methylthiazole;5-(2-Hydroxyethyl)-4-methylthiazole;4-methyl-5-(2-hydroxyethyl)-thiazole;4-Methyl-5-(2-hydroxyethyl)thiazole;5-Thiazoleethanol, 4-methyl-;MHT;4-Methyl-5-(.beta.-hydroxyethyl)thiazole;Sulfurol;THZ;2-(4-methyl-1,3-thiazol-5-yl)ethanol;4-Methyl-5-hydroxyethylthiazole or Sulfurol;Hemineurine;4-Methyl-5-thiazole ethanole;
EINECS: 205-272-6
Density: 1.206 g/cm3
Melting Point: <25 °C
Boiling Point: 272.4 °C at 760 mmHg
Flash Point: 109.7 °C
Appearance: Colorless to light yellow liquid
Hazard Symbols: IrritantXi
Risk Codes: 36/37/38
Safety: 26-36-24/25-7/9
PSA: 61.36000
LogP: 0.98630
Synthetic route
656-53-1

acetic acid 2-(4-methyl-thiazol-5-yl)-ethyl ester

137-00-8

5-hydroxyethyl-4-methylthiazole

Conditions
ConditionsYield
With water; sodium hydroxide In toluene Industrial scale;100%
With sodium hydroxide
With hydrogenchloride
616-47-7

1-methyl-1H-imidazole

73333-47-8

1'-methylthiaminium diperchlorate

A

137-00-8

5-hydroxyethyl-4-methylthiazole

B

C11H17N5(2+)*2ClO4(1-)

Conditions
ConditionsYield
In methanol for 3.5h; Heating;A n/a
B 94%
1739-84-0

1,2-dimethyl-1H-imidazole

73333-47-8

1'-methylthiaminium diperchlorate

A

137-00-8

5-hydroxyethyl-4-methylthiazole

B

C12H19N5(2+)*2ClO4(1-)

Conditions
ConditionsYield
In methanol for 3.5h; Heating;A n/a
B 94%
109-06-8

α-picoline

73333-47-8

1'-methylthiaminium diperchlorate

A

137-00-8

5-hydroxyethyl-4-methylthiazole

B

C13H18N4(2+)*2ClO4(1-)

Conditions
ConditionsYield
In methanol for 2.2h; Heating;A n/a
B 80%
108-89-4

picoline

73333-47-8

1'-methylthiaminium diperchlorate

A

137-00-8

5-hydroxyethyl-4-methylthiazole

B

C13H18N4(2+)*2ClO4(1-)

Conditions
ConditionsYield
In methanol for 3.8h; Heating;A n/a
B 76%
273939-32-5

5-(2-((tert-butyldimethylsilyl)oxy)ethyl)-4-methylthiazole

137-00-8

5-hydroxyethyl-4-methylthiazole

Conditions
ConditionsYield
With potassium hydrogen difluoride In methanol at 60℃; for 17h;75%
4556-23-4

pyridine-4-thiol

73333-47-8

1'-methylthiaminium diperchlorate

A

137-00-8

5-hydroxyethyl-4-methylthiazole

B

4-Amino-1,2-dimethyl-5-(pyridin-4-ylsulfanylmethyl)-pyrimidin-1-ium; perchlorate

Conditions
ConditionsYield
With sodium hydroxide In methanol for 3h; Heating;A n/a
B 71%
5858-17-3

3,4-dichlorothiophenol

73333-47-8

1'-methylthiaminium diperchlorate

A

137-00-8

5-hydroxyethyl-4-methylthiazole

B

4-Amino-5-(3,4-dichloro-phenylsulfanylmethyl)-1,2-dimethyl-pyrimidin-1-ium; perchlorate

Conditions
ConditionsYield
With sodium hydroxide In methanol for 1h; Heating;A n/a
B 69%
767-00-0

4-cyanophenol

73333-47-8

1'-methylthiaminium diperchlorate

A

137-00-8

5-hydroxyethyl-4-methylthiazole

B

4-Amino-5-(4-cyano-phenoxymethyl)-1,2-dimethyl-pyrimidin-1-ium; perchlorate

Conditions
ConditionsYield
With sodium hydroxide In methanol for 4h; Heating;A n/a
B 68%
583-58-4

3,4-Lutidin

73333-47-8

1'-methylthiaminium diperchlorate

A

137-00-8

5-hydroxyethyl-4-methylthiazole

B

C14H20N4(2+)*2ClO4(1-)

Conditions
ConditionsYield
In methanol for 24h; Heating;A n/a
B 64%
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    Product Name: 5-(2-Hydroxyethyl)-4-methylthiazole CAS: 137-00-8 MF: C6H9NOS MW: 143.21 EINECS: 205-272-6 Mol File: 137-00-8.mol 5-(2-Hydroxyethyl)-4-methylthiazole Structure 5-(2-Hydroxyethyl)-4-methylthiazole Chemical Properties

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  • 5-(2-Hydroxyethyl)-4-methylthiazole CAS:137-00-8

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Chemistry

Molecular Formula: C6H9NOS
Molecular Weight: 143.21
EINECS: 205-272-6
Index of Refraction: 1.564
Molar Refractivity: 38.63 cm3
Molar Volume: 118.7 cm3
Surface Tension: 49.8 dyne/cm
Density: 1.206 g/cm3
Flash Point: 109.7 °C
Enthalpy of Vaporization: 53.95 kJ/mol
Boiling Point: 272.4 °C at 760 mmHg
Vapour Pressure: 0.00297 mmHg at 25 °C
Sensitive: Stench
Appearance: Colorless to light yellow liqui
Structure of 4-Methyl-5-thiazoleethanol (CAS NO.137-00-8):
                     
IUPAC Name: 2-(4-Methyl-1,3-thiazol-5-yl)ethanol
Canonical SMILES: CC1=C(SC=N1)CCO
InChI: InChI=1S/C6H9NOS/c1-5-6(2-3-8)9-4-7-5/h4,8H,2-3H2,1H3
InChIKey: BKAWJIRCKVUVED-UHFFFAOYSA-N
Product Category of 4-Methyl-5-thiazoleethanol (CAS NO.137-00-8): Thiazole;Alkohols;thiazole Flavor

Uses

 4-Methyl-5-thiazoleethanol (CAS NO.137-00-8) is used for nuts, dairy products, meat products, etc, and also is used as pharmaceutical intermediates.

Toxicity Data With Reference

 4-Methyl-5-thiazoleethanol (CAS NO.137-00-8) hasn't been listed as a carcinogen by NTP, IARC, ACGIH, or CA Prop 65.

Safety Profile

Hazard Codes:   Xi
The Risk Statements:
36/37/38:  Irritating to eyes, respiratory system and skin 
The Safety Statements:
26:  In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 
36:  Wear suitable protective clothing 
7/9:  Keep container tightly closed and in a well-ventilated place 
24/25:  Avoid contact with skin and eyes 
WGK Germany: 3
F:13
Hazard Note:  Irritant/Stench

Specification

 4-Methyl-5-thiazoleethanol , its cas register number is 137-00-8. It also can be called Sulfurol ; 4-Methyl-5-(2'-hydroxyethyl)-thiazole ; 5-(2-Hydroxyethyl)-4-methylthiazole ; 4-Methyl-5-beta-hydroxyethyl thiazole ; and 4-Methyl-5-hydroxyethylthiazole . It is hazardous, so the first aid measures and others should be known. Such as: When on the skin: Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes. Or in the eyes: Immediately flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. While, it's inhaled: Remove from exposure and move to fresh air immediately. Then you have the ingesting of the product: Do NOT induce vomiting. If conscious and alert, rinse mouth and drink 2-4 cupfuls of milk or water.
In addition,  4-Methyl-5-thiazoleethanol (CAS NO.137-00-8)  could be stable under normal temperatures and pressures. It is not compatible with strong oxidizing agents, and you must not take it with incompatible materials. And also prevent it to broken down into hazardous decomposition products: Nitrogen oxides, carbon monoxide, oxides of sulfur, irritating and toxic fumes and gases, carbon dioxide, nitrogen.

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