Journal of Physical Chemistry p. 3683 - 3685 (1987)
Update date:2022-07-29
Topics:
Su, Timothy
Su, Aaron C. L.
Viggiano, A. A.
Paulson, John F.
The rate constants for the reactions of F-, CF3-, C2F5-, C3F7-, and C4F9- with C2F4 and C3F6 have been measured in the gas phase at 295 K in a selected ion flow tube (SIFT).Most of the observed reactions involve association.F- transfer is observed only from CF3-.All ions studied except C4F9- react with C3F6 with near unit efficiency.Only F- and CF3- were observed to react with C2F4.
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