Journal of Organic Chemistry p. 13488 - 13499 (2017)
Update date:2022-08-04
Topics:
Reddy, Arava Amaranadha
Prasad, Kavirayani R.
Synthesis of β-sulfinamido ketones was accomplished by the addition of silyl enol ethers derived from arylmethyl ketones to chiral sulfinimines in excellent yield and selectivity. Application of the formed β-amino substituted ketones is exemplified in the total synthesis of sphingolipid HPA-12 and the sedamine alkaloids.
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