PREPARATION OF BOTH ENANTIOMERS OF A CHIRAL LACTONE THROUGH COMBINED MICROBIOLOGICAL REDUCTION AND OXIDATION

DOI: 10.1016/S0040-4039(00)95923-9

Source and publish data:

Tetrahedron Letters p. 1109 - 1112 (1987)

Update date:2022-08-03

Topics:

Authors:

Ouazzani-Chahdi, Jamal

Buisson, Didier

Azerad, Robert

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Article abstract of DOI:10.1016/S0040-4039(00)95923-9

The Baeyer-Williger-like oxidation of (R,S)-2,2,5,5-tetramethyl-4-hydroxy-cyclohexanone by several fungal strains was highly enantioselective, affording a rearranged (S)-hydroxy-γ-lactone.The recovery of the nearly optically pure (R)-hydroxyketone allowed

Full text of DOI:10.1016/S0040-4039(00)95923-9

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